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Key Documents

17550

Sigma-Aldrich

2-(Bromomethyl)acrylic acid

purum, ≥97.0% (T)

Synonym(s):

α-(Bromomethyl)acrylic acid, 2-(Bromomethyl)propenoic acid

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About This Item

Linear Formula:
CH2=C(CH2Br)COOH
CAS Number:
Molecular Weight:
164.99
Beilstein:
2426204
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:

grade

purum

Assay

≥97.0% (T)

mp

68-73 °C
70-73 °C (lit.)

storage temp.

2-8°C

SMILES string

OC(=O)C(=C)CBr

InChI

1S/C4H5BrO2/c1-3(2-5)4(6)7/h1-2H2,(H,6,7)

InChI key

NOOYFQLPKUQDNE-UHFFFAOYSA-N

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Other Notes

Preparation of the corresponding Wittig-Horner reagents; The ethyl ester is used for Reformatskii-type reactions giving α-methylene-γ-lactones

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H. Duttmann et al.
Chemische Berichte, 112, 3480-3480 (1979)
K. Ramarajan et al.
Organic Syntheses, 59, 2080-2080 (1980)

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