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07750

Supelco

N,N-Dimethyl-p-phenylenediamine

for spectrophotometric det. of SO42-, S2-, ≥97.0%

Synonym(s):

4-(Dimethylamino)aniline, 4-Amino-N,N-dimethylaniline, N,N-Dimethyl-1,4-phenylenediamine, DMPPDA

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About This Item

Linear Formula:
(CH3)2NC6H4NH2
CAS Number:
Molecular Weight:
136.19
Beilstein:
508105
EC Number:
MDL number:
UNSPSC Code:
41116105
PubChem Substance ID:
NACRES:
NA.21

Quality Level

Assay

≥97.0% (GC)
≥97.0%

quality

for spectrophotometric det. of SO42-, S2-

technique(s)

UV/Vis spectroscopy: suitable

bp

262 °C (lit.)

mp

34-36 °C (lit.)

storage temp.

2-8°C

SMILES string

CN(C)c1ccc(N)cc1

InChI

1S/C8H12N2/c1-10(2)8-5-3-7(9)4-6-8/h3-6H,9H2,1-2H3

InChI key

BZORFPDSXLZWJF-UHFFFAOYSA-N

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Application

N,N-Dimethyl-p-phenylenediamine (DMPD) may be used as a reagent for the determination of amoxicillin in aqueous solutions and pharmaceutical formulations by ultraviolet-visible (UV-vis) spectrophotometry.
It may also be used for the estimation of iron and copper based on the catalytic oxidation of DMPD with hydrogen peroxide (H2O2) and 1,3-phenylenediamine in the presence of H2O2 respectively by flow injection analysis (FIA) coupled with UV-vis spectrophotometry.

Other Notes

Reagent for the spectrophotometric det. of SO42- and S2-

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Oral - Acute Tox. 3 Inhalation

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

195.8 °F - closed cup

Flash Point(C)

91 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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P K Zutshi et al.
Talanta, 17(10), 1014-1018 (1970-10-01)
The sensitivity and reproducibility of the Methylene Blue method for gaseous sulphide estimation have been investigated with respect to physical conditions and the concentrations of the reagents, especially sulphuric add. A new design of absorber is proposed to minimize gas-phase
Determination of total and dissolved amount of iron in water samples using catalytic spectrophotometric flow injection analysis
Lunvongsa S, et al.
Talanta, 68(3), 969-973 (2006)
Novel catalytic oxidative coupling reaction of N, N-dimethyl-p-phenylenediamine with 1, 3-phenylenediamine and its applications to the determination of copper and iron at trace levels by flow injection technique
Lunvongsa S, et al.
Analytica Chimica Acta, 576(2), 261-269 (2006)
Spectrophotometric determination of amoxicillin by reaction with N, N-dimethyl-p-phenylenediamine and potassium hexacyanoferrate (III)
Al-Abachi MQ, et al.
Analytica Chimica Acta, 554(1-2), 184-189 (2005)
N.A. Matheson
Analyst, 99, 577-577 (1974)

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