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926108

Sigma-Aldrich

(S)-RUCY™-XylBINAP

Takasago

Synonym(s):

RuCl[(S)-daipena][(S)-xylbinap]

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About This Item

Empirical Formula (Hill Notation):
C71H73ClN2O2P2Ru
CAS Number:
1312713-89-5
Molecular Weight:
1184.82
UNSPSC Code:
12352116
NACRES:
NA.22

Quality Level

100

form

powder

reaction suitability

reagent type: ligand

functional group

phosphine

Related Categories

Application

(S)-RUCY™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.

Other Notes

Chiral Ruthenabicyclic Complexes: Precatalysts for Rapid, Enantioselective, and Wide-Scope Hydrogenation of Ketones

Legal Information

Product of Takasago.

For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and

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