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908185

Sigma-Aldrich

3DPA2FBN

≥95%

Synonym(s):

2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile

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About This Item

Empirical Formula (Hill Notation):
C43H30F2N4
CAS Number:
1403850-00-9
Molecular Weight:
640.72
UNSPSC Code:
12352101
NACRES:
NA.22

Assay

≥95%

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Photocatalysis

mp

280-281 °C

photocatalyst activation

455 nm

Related Categories

Application

3DPA2FBN is cyanoarene-based donor-acceptor photocatalyst developed by the Zeitler group. While this catalyst has a balanced redox profile, allowing for its use in a variety of transformations, it stands out as the most reducing catalyst of the family.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A Toolbox Approach To Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry: Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor-Acceptor Cyanoarenes

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Elisabeth Speckmeier et al.
Journal of the American Chemical Society, 140(45), 15353-15365 (2018-10-03)
The targeted choice of specific photocatalysts has been shown to play a critical role for the successful realization of challenging photoredox catalytic transformations. Herein, we demonstrate the successful implementation of a rational design strategy for a series of deliberate structural

Related Content

Photoredox Catalysis

Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.

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