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753971

Sigma-Aldrich

PBTTT-C14

Synonym(s):

Poly[2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene]

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About This Item

Linear Formula:
(C42H62S4)n
CAS Number:
UNSPSC Code:
12352103
NACRES:
NA.23

form

powder

mol wt

Mw >50,000

mp

>200 °C

semiconductor properties

(mobility=1.3 cm2/V·s)

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General description

PBTTT-C14 is a semiconducting material which is used as a hole transporting material (HTM). It has an ordered structure and crystal orientation which result in a high performance conducting material.

Application

PBTTT-C14 based conjugated polymers can potentially be used in combination with fullerenes and P3HT for the fabrication of a wide range of devices like organic field effect transistors (OFETs), organic photovoltaics (OPVs), solar cells (SCs) and photodiodes.

Legal Information

Sold under license from Merck KGaA, Darmstadt, Germany.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Hybrid n-GaN and polymer interfaces: Model systems for tunable photodiodes.
Kumar P, et al.
Organic Electronics, 14(11), 2818-2825 (2013)
Structural, electronic, and linear optical properties of organic photovoltaic PBTTT-C14 crystal.
Li L, et al.
J. Chem. Phys. , 138(16), 164503-164503 (2013)
High carrier mobility polythiophene thin films: structure determination by experiment and theory.
DeLongchamp DM, et al.
Advanced Materials, 19(6), 833-837 (2007)
Solvent driven performance in thin floating-films of PBTTT for organic field effect transistor: role of macroscopic orientation.
Pandey M.
Organic Electronics, 43(6), 240-246 (2017)
Intercalated vs Nonintercalated Morphologies in Donor-Acceptor Bulk Heterojunction Solar Cells: PBTTT: Fullerene Charge Generation and Recombination Revisited.
Collado-Fregoso E, et al.
The Journal of Physical Chemistry Letters, 8(17), 4061-4068 (2017)

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