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Sigma-Aldrich

Iron(III) chloride

greener alternative

anhydrous, powder, ≥99.99% trace metals basis

Synonym(s):

Ferric chloride, Iron trichloride, Molysite

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About This Item

Linear Formula:
FeCl3
CAS Number:
Molecular Weight:
162.20
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

vapor density

5.61 (vs air)

vapor pressure

1 mmHg ( 194 °C)

Assay

≥99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: iron

greener alternative product characteristics

Catalysis
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sustainability

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impurities

≤100.0 ppm Trace Metal Analysis

mp

304 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

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General description

Iron(III) chloride is brownish to black crystalline solid that is highly soluble in water. As a moderately strong Lewis acid, it highly reactive with bases and capable of forming complex ions. It is widely used as a iron precursor in the field of catalysis, solar cells and batteries.
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Application

Iron(III) chloride can be used:
  • As a precursor to fabricate nano-sized Fe-N-C catalysts for proton exchange membrane(PEM) fuel cells. FeCl3 iron precursor, helps to achieve the lowest charge transfer resistance and high peak power density.
  • As an oxidant to prepare FeOCl@PPy cathode materials for Li-ion batteries with good cycling stability.
  • As a precursor to fabricate amorphous multifunctional am-Fe–Bi/NF electrode for rechargeable Zinc-air batteries.
  • To synthesize Fe3O4@nanocellulose/TiCl nano fillers for dye-sensitized solar cells to reduce the crystallinity of the polymer.

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Photoredox chemistry of iron (III) chloride and iron (III) perchlorate in aqueous media. A comparative study.
David F and David PG.
The Journal of Physical Chemistry, 80(6), 579-583 (1976)
Eagleson M.
Concise Encyclopedia Chemistry, 553-553 (1994)

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