309281

Iron(III) perchlorate hydrate

crystalline

• Synonym(s): Perchloric acid iron(III) salt hydrate
• Linear Formula: Fe(ClO₄)₃ · xH₂O
• CAS Number: 15201-61-3
• Molecular Weight: 354.20 (anhydrous basis)
• EC Number: 236-908-0
• MDL number: MFCD00149705
• UNSPSC Code: 12352000
• PubChem Substance ID: 24858725
• NACRES: NA.22

Properties

• form: crystalline
• reaction suitability: reagent type: oxidant
• impurities: <0.10% chloride
• color: yellow
• SMILES string: [Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• InChI key: PFPIMAZLJXJVAN-UHFFFAOYSA-K

Description

Application

Catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization

Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.

It can be used as a catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Fulleroxazolidines
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Safety Information

• Pictograms: GHS03,GHS07
• Signal Word: Danger
• Hazard Statements: H272,H315,H319,H335
• Precautionary Statements: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves