227951

Chloro(1,5-cyclooctadiene)rhodium(I) dimer

98%

• Synonym(s): 1,5-Cyclooctadienerhodium(I) chloride dimer, Bis(1,5-cyclooctadiene)dirhodium(I) dichloride, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer, [Rh(COD)Cl]₂
• Empirical Formula (Hill Notation): C₁₆H₂₄Cl₂Rh₂
• CAS Number: 12092-47-6
• Molecular Weight: 493.08
• EC Number: 235-157-6
• MDL number: MFCD00012415
• UNSPSC Code: 12161600
• PubChem Substance ID: 24853665
• NACRES: NA.22

Properties

• Assay: 98%
• form: solid
• reaction suitability: core: rhodium; reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 243 °C (dec.) (lit.)
• greener alternative category: Aligned,
• SMILES string: Cl[Rh].Cl[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
• InChI key: QSUDXYGZLAJAQU-MIXQCLKLSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Efficient and Selective Catalysts for Asymmetric Synthesis

Catalyst for coupling 1,3-dienes with activated hydrocarbons and for preparing chiral complexes.

Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H319
• Precautionary Statements: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves