- New approach to resolve the humidity problem in VOC determination in outdoor air samples using solid adsorbent tubes followed by TD-GC-MS.
New approach to resolve the humidity problem in VOC determination in outdoor air samples using solid adsorbent tubes followed by TD-GC-MS.
The Science of the total environment (2017-05-26)
Alba Maceira, Laura Vallecillos, Francesc Borrull, Rosa Maria Marcé
PMID28535600
要旨
This study describes the humidity effect in the sampling process by adsorbent tubes followed by thermal desorption and gas chromatography-mass spectrometry (TD-GC-MS) for the determination of volatile organic compounds (VOCs) in air samples and evaluates possible solutions to this problem. Two multi-sorbent bed tubes, Tenax TA/Carbograph 1TD and Carbotrap B/Carbopack X/Carboxen 569, were tested in order to evaluate their behaviour in the presence of environmental humidity. Humidity problems were demonstrated with carbon-based tubes, while Tenax-based tubes did not display any influence. Silica gel, a molecular sieve and CaCl
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Supelco
SPMEファイバーアセンブリー ジビニルベンゼン/カルボキセン/ポリジメチルシロキサン (DVB/CAR/PDMS), needle size 24 ga, StableFlex
Supelco
SPMEファイバーアセンブリー ジビニルベンゼン/カルボキセン/ポリジメチルシロキサン (DVB/CAR/PDMS), needle size 23 ga, StableFlex, for use with autosampler
Supelco
SPMEファイバーアセンブリー ジビニルベンゼン/カルボキセン/ポリジメチルシロキサン (DVB/CAR/PDMS), needle size 24 ga, for use with manual holder
Supelco
ORBO™ Carboxen-564チューブ, W,F,F separators, O.D. × L 6 mm × 75 mm, pkg of 25 ea, for analyte group MEK (methylethyl ketone)
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SPMEファイバーアセンブリー ジビニルベンゼン/カルボキセン/ポリジメチルシロキサン (DVB/CAR/PDMS), needle size 23 ga, StableFlex, for use with manual holder or autosampler, fiber L 2 cm
Supelco
SPMEファイバーアセンブリー ジビニルベンゼン/カルボキセン/ポリジメチルシロキサン (DVB/CAR/PDMS), needle size 24 ga, StableFlex, for use with autosampler
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Carboxen® 564特殊洗浄済み(20/45)、400/200 mg入りORBO™ 78 HBR, W,W,W separators, O.D. × L 6 mm × 110 mm, pkg of 25 ea
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Carbotrap® 300, glass TD tube, fritted, O.D. × I.D. × L 6 mm × 4 mm × 7 in., preconditioned, pkg of 1 ea
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SPMEファイバー・アセンブリカルボキセン/ポリジメチルシロキサン(CAR/PDMS), df 75 μm(CAR/PDMS, for use with manual holder, needle size 24 ga
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FLM Carbopack™ X Deactivated Stainless Steel TD Tube, preconditioned, pkg of 10 tubes, O.D. × L 1/4 in. (6.35 mm) × 3 1/2 in. (89 mm)
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SPMEファイバー・アセンブリカルボキセン/ポリジメチルシロキサン(CAR/PDMS), df 85 μm(CAR/PDMS, needle size 24 ga, StableFlex, for use with autosampler
Supelco
SPMEファイバー・アセンブリカルボキセン/ポリジメチルシロキサン(CAR/PDMS), df 85 μm(CAR/PDMS, needle size 23 ga, StableFlex, for use with autosampler
Supelco
SPMEファイバー・アセンブリカルボキセン/ポリジメチルシロキサン(CAR/PDMS), df 75 μm(CAR/PDMS, needle size 24 ga, for use with autosampler
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ORBO™ 101 Carbotrap® B (20/40), 100/50 mg, W,W,W separators, O.D. × L 6 mm × 70 mm, pkg of 25 ea
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SPMEファイバー・アセンブリカルボキセン/ポリジメチルシロキサン(CAR/PDMS), df 85 μm(CAR/PDMS, needle size 24 ga, for use with manual holder, StableFlex fiber
Supelco
SPMEファイバー・アセンブリカルボキセン/ポリジメチルシロキサン(CAR/PDMS), df 75 μm(CAR/PDMS, needle size 23 ga, for use with autosampler
Supelco
Carbotrap® 300, O.D. × L 1/4 in. × 3 1/2 in., stainless steel TD tube, Sealed with Brass Endcaps, preconditioned, pkg of 10 ea
Supelco
Carbotrap® 300, O.D. × L 1/4 in. × 3 1/2 in., stainless steel TD tube, preconditioned, pkg of 10 ea
Supelco
SPMEファイバー・アセンブリカルボキセン/ポリジメチルシロキサン(CAR/PDMS), df 75 μm(CAR/PDMS, needle size 23 ga, for use with manual holder