- Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media.
Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media.
Chemical communications (Cambridge, England) (2002-07-19)
Steven V Ley, Chandrashekar Ramarao, Richard S Gordon, Andrew B Holmes, Angus J Morrison, Ian F McConvey, Ian M Shirley, Stephen C Smith, Martin D Smith
PMID12122701
要旨
Palladium(II) acetate microencapsulated in polyurea (MC-[Pd]) is an economical and versatile heterogeneous catalyst for a range of phosphine-free cross-coupling reactions in both conventional solvents and supercritical carbon dioxide (scCO2); the catalyst can be recovered by a simple filtration and recycled up to four times.