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Merck

Regioselective copolymerization of acryl sucrose monomers.

The Journal of organic chemistry (2004-10-23)
Maria Teresa Barros, Krasimira T Petrova, Ana Maria Ramos
要旨

1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.

材料
製品番号
ブランド
製品内容

Sigma-Aldrich
スクロース, ≥99.5% (GC), BioXtra
Sigma-Aldrich
4-(ジメチルアミノ)ピリジン, ReagentPlus®, ≥99%
Sigma-Aldrich
テトラブチルアンモニウムヨージド, reagent grade, 98%
Sigma-Aldrich
tert-ブチル(クロロ)ジフェニルシラン, 98%
Sigma-Aldrich
N,N-ジメチルホルムアミド, anhydrous, 99.8%