コンテンツへスキップ
Merck
  • C-acylations of polymeric phosphoranylidene acetates for C-terminal variation of peptide carboxylic acids.

C-acylations of polymeric phosphoranylidene acetates for C-terminal variation of peptide carboxylic acids.

Organic letters (2007-02-20)
Adeeb El-Dahshan, Steffen Weik, Jörg Rademann
要旨

C-Acylations of polymer-supported 2-phosphoranylidene acetates ("linker reagents") with protected amino acids yielded 2-acyl-2-phosphoranylidene acetates as flexible intermediates for the C-terminal variation of carboxylic acids: peptidyl-2,3-diketoesters, peptidyl vinyl ketones, peptidyl-2-ketoaldehydes, and 1,3-diamino-2-hydroxy-propanes were obtained as products. [reaction: see text]

材料
製品番号
ブランド
製品内容

Sigma-Aldrich
1,3-ジアミノプロパン, ≥99%
現在、価格および在庫状況を閲覧できません。
Sigma-Aldrich
1,3-ジアミノプロパン 二塩酸塩, 98%
現在、価格および在庫状況を閲覧できません。