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Merck

CRM56578

Supelco

Prallethrin

mixture of stereoisomers, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

別名:

(RS)-2-Methyl-4-oxo-3-prop-2-ynylcyclopent-2-enyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate

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About This Item

実験式(ヒル表記法):
C19H24O3
CAS番号:
分子量:
300.39
MDL番号:
UNSPSCコード:
41116107
NACRES:
NA.24

グレード

certified reference material
TraceCERT®

品質水準

製品種目

TraceCERT®

シェルフライフ

limited shelf life, expiry date on the label

メーカー/製品名

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

フォーマット

neat

保管温度

−20°C

SMILES記法

C\C(C)=C/C1C(C(=O)OC2CC(=O)C(CC#C)=C2C)C1(C)C

InChI

1S/C19H24O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h1,9,14,16-17H,8,10H2,2-6H3

InChI Key

SMKRKQBMYOFFMU-UHFFFAOYSA-N

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詳細

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Prallethrin is an insecticide that belongs to the family of non-fluorinated pyrethroids and is used against mosquitoes, houseflies, termites, and other insect vectors. It acts by modulating the sodium channels present across the axonal membranes in neurons.
As per the Regulation (EC) No. 1107/2009, repealing the directive 91/414/EEC, prallethrin is not approved for use as a plant protection agent in the European Union.

アプリケーション

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The prallethrin CRM may also find the following uses:

  • Determination of seven pyrethroids and piperonyl butoxide in indoor air following their passive sampling by a method combining thermal desorption with gas chromatography-mass spectrometry (GC-MS)
  • Multi-residue analysis of 8 pesticides in bovine, chicken, and swine muscle and liver samples by a method coupling modified QuEChERS extraction to LC-MS/MS
  • Analysis of 60 pesticide residues in various vegetable and fruit samples by solid-phase extraction (SPE) and ultra-high-performance liquid chromatography/time-of-flight mass spectrometry (UHPLC-TOF/MS)
  • Development of an electron ionization gas chromatography-mass spectrometry (GC-MS) method to determine l3 pyrethroid insecticide residues in whole blood samples
  • Simultaneous evaluation of nine pyrethroids in household pyrethroid products (mosquito coils and aerosols) by capillary gas chromatography with FID detection
  • Study the analysis of nine pyrethroids by combining hollow fiber-based liquid-phase microextraction (HF-LPME) with gas chromatography-mass spectrometry (GC/MS) in water samples

法的情報

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

ピクトグラム

Skull and crossbonesEnvironment

シグナルワード

Danger

危険有害性情報

危険有害性の分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

保管分類コード

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

引火点(°F)

282.2 °F - closed cup

引火点(℃)

139 °C - closed cup


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

消防法

第4類:引火性液体
第三石油類
危険等級III
非水溶性液体

Jan Code

CRM56578-50MG:
CRM56578-BULK:
CRM56578-100MG:


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試験成績書(COA)

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I San Román et al.
Talanta, 100, 246-253 (2012-11-13)
A simple, easy-to-use, efficient and environmentally friendly method has been developed for the simultaneous analysis of nine pirethroid pesticides in water samples by the combination of hollow fibre-based liquid-phase microextraction (HF-LPME) and gas chromatography-mass spectrometry (GC/MS). For the developed method
K Hamamoto et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 34(7), 1162-1171 (2017-04-14)
Many multiresidue methods for the determination of pesticides in vegetables and fruits have been reported to date. However, few such methods have been employed to investigate pesticide residues in animal tissue. In this study, an LC-MS/MS multiresidue method coupled with
Insecticidal efficacy of a binary combination of cyphenothrin and prallethrin, applied as surface treatment against four major stored-product insects
Karanika C, et al.
Journal of Stored Products Research, 80, 41-49 (2019)
Atmakuru Ramesh et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 802(2), 371-376 (2004-03-17)
A new rapid and sensitive electron ionization gas chromatography-mass spectrometry method in selective ion monitoring mode (SIM) was developed for the determination of l3 synthetic pyrethroid insecticide molecules and their stereo isomers in whole blood. The pyrethroid insecticides investigated are
Hongyuan Yan et al.
Journal of pharmaceutical and biomedical analysis, 51(3), 774-777 (2009-10-31)
A gas chromatographic method was developed for simultaneous determination of nine pyrethroids (permethrin, transallethrin, beta-cypermethrin, prallethrin, tetramethrin, transfluthrin, cyphenothrin, phenothrin, imiprothrin) in indoor insecticide products using dibutyl phthalate and iso-octyl phthalate as two internal standards. Parameters affecting the extraction and

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