42215

2,4-Dinitrophenylhydrazine Phosphoric acid solution

for derivatization (of aldehydes and ketones), LiChropur^™, substitute for the explosive solid, ~0.2 M (~4%)

• 実験式（ヒル表記法）: C₆H₆N₄O₄
• CAS番号: 125038-14-4
• 分子量: 198.14
• Beilstein: 6258433
• MDL番号: MFCD01863021
• UNSPSCコード: 41116105
• PubChem Substance ID: 329756206
• NACRES: NA.22

特性

• グレード: for derivatization (of aldehydes and ketones)
• 形状: liquid
• 品質: LiChropur^™
• 組成: 2,4-dinitrophenylhydrazine ; ethanol ; phosphoric acid
• 濃度: ~0.2 M (~4%)
• テクニック: thin layer chromatography (TLC): suitable
• 密度: 1.35 g/mL at 20 °C
• SMILES記法: OP(O)(O)=O.NNc1ccc(cc1[N+]([O-])=O)[N+]([O-])=O
• InChI: 1S/C6H6N4O4.H3O4P/c7-8-5-2-1-4(9(11)12)3-6(5)10(13)14;1-5(2,3)4/h1-3,8H,7H2;(H3,1,2,3,4)
• InChI Key: RYSWHUOYGUCXQB-UHFFFAOYSA-N

詳細

アプリケーション

• Visible-light excitable Eu(3+)-induced hyaluronic acid-chitosan aggregates with heterocyclic ligands for sensitive and fast recognition of hazardous ions: Utilizes 1,10-phenanthroline monohydrate in environmental sensing applications to detect hazardous ions efficiently (Aleem AR, Ding W, Liu J, Li T, Guo Y, Wang Q, Wang Y, Rehman FUL, Kipper MJ, Belfiore LA, Tang J, 2021).


• Structural diversity of copper(I) complexes formed by pyrrole- and dipyrrolylmethane-based diphosphine ligands with cu-X···HN hydrogen bonds: Researches the coordination chemistry of 1,10-phenanthroline monohydrate, highlighting its role in forming novel copper(I) complexes (Kumar S, Mani G, Dutta D, Mishra S, 2014).


• Direct electron transfer from glucose oxidase immobilized on polyphenanthroline-modified glassy carbon electrode: Demonstrates the use of 1,10-phenanthroline monohydrate in biosensor applications for direct electron transfer mechanisms (Oztekin Y, Ramanaviciene A, Yazicigil Z, Solak AO, Ramanavicius A, 2011).

その他情報

アルデヒドやケトンの誘導体化試薬。爆発性固体の代替として使用できます。

法的情報

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

安全性情報

• ピクトグラム: GHS02,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H226,H290,H302,H314
• 注意書き: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Corr. 1B
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 86.0 °F
• 引火点(℃): 30 °C
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter