すべての画像(1)
About This Item
実験式（ヒル表記法）:
C6H2BBrF6KN
分子量:
331.89
MDL番号:
UNSPSCコード:
12352103
PubChem Substance ID:
NACRES:
NA.22
アッセイ
97%
形状
solid
SMILES記法
BrC1=C([B-](F)(F)F)C(C(F)(F)F)=CC=N1.[K+]
InChI
1S/C6H2BBrF6N.K/c8-5-4(7(12,13)14)3(1-2-15-5)6(9,10)11;/h1-2H;/q-1;+1
InChI Key
WGDRKFJAJWNHQI-UHFFFAOYSA-N
アプリケーション
An organotrifluoroborate involved in:
Organotrifluoroborates as versatile and stable boronic acid surrogates.
- Nickel-catalyzed cross-coupling reactions and C-O activation
- Suzuki cross-coupling,
- Copper-catalyzed cross-coupling reactions
- Stereoselective Mukaiyama aldol reactions
Organotrifluoroborates as versatile and stable boronic acid surrogates.
シグナルワード
Warning
危険有害性情報
危険有害性の分類
Eye Irrit. 2 - Skin Irrit. 2
保管分類コード
11 - Combustible Solids
WGK
WGK 3
引火点(°F)
Not applicable
引火点(℃)
Not applicable
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
Jan Code
790397-BULK:
790397-1G:
790397-VAR:
最新バージョンのいずれかを選択してください：
Synthesis of 5-aryl- and 5-heteroaryl-7-carboxyl-8-hydroxyquinaldines through Suzuki cross-coupling reaction with potassium organotrifluoroborates
Synthesis, 4, 619-630 (2010)
Gary A Molander et al.
Organic letters, 12(18), 4022-4025 (2010-08-19)
A general method based on nickel-catalyzed C-O activation of various phenol derivatives with potassium (hetero)aryltrifluoroborates has been developed. A large number of heterobiaryls can be easily obtained with yields up to 99% using methanesulfonate cross-coupling partners.
Copper catalyzed cross-coupling reactions of diaryl ditellurides with potassium aryltrifluoroborate salts
Journal of the Brazilian Chemical Society, 20, 988-992 (2009)
J Michael Ellis et al.
The Journal of organic chemistry, 73(22), 9151-9154 (2008-10-16)
A new synthesis of 3,3'-bioxindoles is reported that is well suited for the preparation of unsymmetrical structures. In the key step, 3-hydroxy-3,3'-bioxindoles are constructed by Mukaiyama aldol reaction of 2-siloxyindoles with isatins. These tertiary carbinols are formed in high diastereoselectivities
Gary A Molander et al.
The Journal of organic chemistry, 74(3), 973-980 (2008-12-25)
A wide variety of bench-stable potassium heteroaryltrifluoroborates were prepared, and general reaction conditions were developed for their cross-coupling to aryl and heteroaryl halides. The cross-coupled products were obtained in good to excellent yields. This method represents an efficient and facile
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