698148

3-ニトロフェニルボロン酸 MIDA エステル

97%

• 別名: 6-メチル-2-(3-ニトロフェニル)-1,3,6,2-ジオキサザボロカン-4,8-ジオン
• 実験式（ヒル表記法）: C₁₁H₁₁BN₂O₆
• CAS番号: 1311484-45-3
• 分子量: 278.03
• MDL番号: MFCD11215228
• UNSPSCコード: 12352103
• PubChem Substance ID: 329761985
• NACRES: NA.22

特性

• アッセイ: 97%
• 形状: powder
• mp: 211-215 °C
• SMILES記法: CN1CC(=O)OB(OC(=O)C1)c2cccc(c2)[N+]([O-])=O
• InChI: 1S/C11H11BN2O6/c1-13-6-10(15)19-12(20-11(16)7-13)8-3-2-4-9(5-8)14(17)18/h2-5H,6-7H2,1H3
• InChI Key: COEHPTUYNRXODY-UHFFFAOYSA-N

詳細

アプリケーション

Suzuki Cross-Coupling with MIDA Boronates

3-Nitrophenylboronic acid MIDA ester is a stable boronic acid surrogate that can be used as a reagent in the Suzuki-Miyaura cross-coupling reactions to prepare useful building blocks via C-C bond formation. 3-allylnitrobenzene is one of the building blocks prepared from this ester by reacting with allyl bromide in the presence of a palladium catalyst.

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)