497924

6-Cyanohexylzinc bromide solution

0.5 M in THF

• 化学式: NC(CH₂)₆ZnBr
• CAS番号: 312624-28-5
• 分子量: 255.47
• MDL番号: MFCD01316997
• UNSPSCコード: 12352103
• PubChem Substance ID: 24873155
• NACRES: NA.22

特性

• 濃度: 0.5 M in THF
• 密度: 0.944 g/mL at 25 °C
• 保管温度: 2-8°C
• SMILES記法: Br[Zn]CCCCCCC#N
• InChI: 1S/C7H12N.BrH.Zn/c1-2-3-4-5-6-7-8;;/h1-6H2;1H;/q;;+1/p-1
• InChI Key: YDXOVAJDARDUOR-UHFFFAOYSA-M

詳細

アプリケーション

6-Cyanohexylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.
It can also be used as a reactant to synthesize:

• Cyanohexyl substituted aryl derivatives by palladium catalyzed coupling reaction with aryl bromides.
• Methyl 5-(6-cyanohexyl)-3-methylfuran-2-carboxylate, a key intermediate which is used in the preparation of cyclic furfuryl ether via Wittig rearrangement.

法的情報

Rieke^®Metals, Inc.の製品です。

Rieke is a registered trademark of Rieke Metals, Inc.

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H319,H335,H336,H351
• 注意書き: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
• 危険有害性の分類: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• ターゲットの組織: Central nervous system, Respiratory system
• 補足的ハザード: EUH014,EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 1.4 °F - closed cup
• 引火点(℃): -17 °C - closed cup