237582

Methyl 2-phenylsulfinylacetate

98%

• 化学式: C₆H₅S(O)CH₂CO₂CH₃
• CAS番号: 14090-83-6
• 分子量: 198.24
• Beilstein: 1953383
• EC Number: 237-936-6
• MDL番号: MFCD00002087
• UNSPSCコード: 12352100
• PubChem Substance ID: 24854255
• NACRES: NA.22

特性

• アッセイ: 98%
• フォーム: solid
• bp: 130-131 °C/0.5 mmHg (lit.)
• mp: 52-54 °C (lit.)
• SMILES記法: COC(=O)CS(=O)c1ccccc1
• InChI: 1S/C9H10O3S/c1-12-9(10)7-13(11)8-5-3-2-4-6-8/h2-6H,7H2,1H3
• InChI Key: JPPXZUDQIXZLIL-UHFFFAOYSA-N

詳細

詳細

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

アプリケーション

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): 235.4 °F - closed cup
• 引火点(℃): 113 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)