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14765

Sigma-Aldrich

Thallium(I) acetate

purum, ≥97.0%

Synonym(s):

TlOAc, Acetic acid thallium(I) salt

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25 G
¥19,200
100 G
¥50,300

¥19,200

Estimated to ship onMay 18, 2025

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25 G
¥19,200
100 G
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About This Item

Linear Formula:
CH3COOTl
CAS Number:
563-68-8
Molecular Weight:
263.43
Beilstein:
3693914
EC Number:
209-257-5
MDL number:
MFCD00013045
UNSPSC Code:
12161600
PubChem Substance ID:
57647193
NACRES:
NA.22

¥19,200

Estimated to ship onMay 18, 2025

Request a Bulk Order

grade

purum

Quality Level

200

Assay

≥97.0%

form

solid

reaction suitability

core: thallium
reagent type: catalyst

SMILES string

CC(=O)O[Tl]

InChI

1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

InChI key

HQOJMTATBXYHNR-UHFFFAOYSA-M

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General description

Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions. [1] [2]

Application

  • Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).

Signal Word

Danger

Hazard Statements

H300 + H330,H373,H411

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

14765-BULK:
14765-VAR:
14765-100G:4548173248394
14765-5G:4548173248417
14765-25G:4548173248400

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM9606
BCCL9073
BCCK0233
BCCH8281
BCCG5515

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Thies, R.W.; Boop, J. L. et al
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Tanaka S, et al.
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
Tanabe T, et al.
ECS Transactions, 13(20), 7-7 (2008)
Grigg, R.; Kennewell, P. et al
Tetrahedron Letters, 33, 7789-7789 (1992)
M Csicsaky et al.
Toxicology, 49(1), 121-129 (1988-04-01)
The toxic effect of thallium added to the bath solution was studied with intra- and extracellular recordings from mammalian nerve-muscle preparations. To elucidate the target region, 3 different functional parameters were studied: (1) Post-synaptic endplate potentials (EPPs) resulting from evoked
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