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09735

Sigma-Aldrich

Ammonium formate

BioUltra, ≥99.0% (calc. based on dry substance, NT)

Synonym(s):

Formic acid ammonium salt

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About This Item

Linear Formula:
HCO2NH4
CAS Number:
540-69-2
Molecular Weight:
63.06
Beilstein:
3625095
EC Number:
208-753-9
MDL number:
MFCD00013103
UNSPSC Code:
12352107
eCl@ss:
39021903
PubChem Substance ID:
329748812
NACRES:
NA.25

product line

BioUltra

Quality Level

200

Assay

≥99.0% (calc. based on dry substance, NT)

form

crystals

impurities

insoluble matter, passes filter test
≤2% water

ign. residue (900 °C)

≤0.1% (as SO4)

pH

5.5-7.5 (25 °C, 1 M in H2O)

mp

119-121 °C (lit.)

solubility

H2O: 1 M at 20 °C, clear, colorless

density

1.26 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Al: ≤5 mg/kg
As: ≤0.1 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Li: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Zn: ≤5 mg/kg

λ

1 M in H2O

UV absorption

λ: 260 nm Amax: ≤0.01
λ: 280 nm Amax: ≤0.01

SMILES string

N.OC=O

InChI

1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3

InChI key

VZTDIZULWFCMLS-UHFFFAOYSA-N

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Application

Ammonium formate can be used to study biological buffers. Ammonium formate has been used in a study to develop an ultrasensitive and selective high performance liquid chromatographic method for one of volatile signaling phytohormones, jasmonic acid (JA). Ammonium formate has also been used in a study to develop and validate a direct injection liquid chromatography-electrospray ionization-tandem mass spectrometric method (LC-ESI-MS/MS) for the rapid and simple determination of 13 phenylalkylamine derivatives.

Other Notes

Buffer component in the separation and purification of glycosaminoglycans from complex systems by affinity chromatography with Polybrene.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

09735-50G:
09735-BULK:
09735-250G:
09735-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM4260
BCCL8711
BCCJ9633
BCCH2525
BCCJ5289

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B A Hodson et al.
Journal of chromatography, 565(1-2), 416-423 (1991-04-19)
A new system for the isolation and purification of glycosaminoglycans (GAGs) and related molecules from complex systems such as plasma is described. Affinity chromatography which exploits the very high affinity between the polymeric base Polybrene and sulphated polysaccharides was used.
Anne M Filppula et al.
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Sai Duan et al.
Physical chemistry chemical physics : PCCP, 15(13), 4625-4633 (2013-02-21)
Local structures and adsorption energies of a formic acid molecule and its decomposed intermediates (H, O, OH, CO, HCOO, and COOH) on highly electrocatalytically active mushroom-like Au-core@Pd-shell@Pt-cluster nanoparticles with two atomic layers of the Pd shell and stoichiometric Pt coverage
Therese Fagerqvist et al.
Journal of neurochemistry, 126(1), 131-144 (2013-02-01)
Inclusions of intraneuronal alpha-synuclein (α-synuclein) can be detected in brains of patients with Parkinson's disease and dementia with Lewy bodies. The aggregation of α-synuclein is a central feature of the disease pathogenesis. Among the different α-synuclein species, large oligomers/protofibrils have
Jo Philips et al.
Journal of contaminant hydrology, 147, 25-33 (2013-03-19)
Acidification due to microbial dechlorination of trichloroethene (TCE) can limit the bio-enhanced dissolution of TCE dense non-aqueous phase liquid (DNAPL). This study related the dissolution enhancement of a TCE DNAPL to the pH buffer capacity of the medium and the
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