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Safety Information

07-3750

Sigma-Aldrich

Diiodomethane

SAJ first grade, ≥98.0%

Synonym(s):

Methylene iodide

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About This Item

Empirical Formula (Hill Notation):
CH2I2
CAS Number:
Molecular Weight:
267.84
Beilstein:
1696892
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:

grade

SAJ first grade

vapor density

9.25 (vs air)

Assay

≥98.0%

form

liquid

availability

available only in Japan

bp

67-69 °C/11 mmHg (lit.)

mp

5-8 °C (lit.)

density

3.325 g/mL at 25 °C (lit.)

SMILES string

ICI

InChI

1S/CH2I2/c2-1-3/h1H2

InChI key

NZZFYRREKKOMAT-UHFFFAOYSA-N

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Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

07-3750-2-25G-J:
07-3750-5-500G-J:


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Yan Li et al.
Colloids and surfaces. B, Biointerfaces, 75(2), 550-556 (2009-10-24)
The self-assembled monolayers (SAMs) with gradient surface free energies were prepared by surface grafting of a binary mixture of methyl and vinyl terminated trimethoxysilanes on hydrophilic glass slides followed by in situ oxidation of vinyl groups into carboxyl groups. Characterized
Razak Kadir et al.
Environmental science & technology, 43(13), 5113-5116 (2009-08-14)
An optical sensor sensitive to BTX has been developed by spin coating a thin film of polyacrylate resin onto a tin- diffused glass optical waveguide. A pair of prism coupler was employed for optical coupling matched with diiodomethane (CH2l2). The
Kevin Cheng et al.
Organic letters, 13(9), 2346-2349 (2011-04-06)
A diastereoselective synthesis of trans-2-substituted cyclopropanols is outlined. Bimetallic CH(2)(ZnI)(2) was found to react with α-chloroaldehydes to give cyclopropanols in yields of 64-89% and dr's ≥ 10:1. The high trans-selectivity resulted from equilibration of the cyclopropoxide intermediates.
T S Meiron et al.
Journal of food science, 72(9), E485-E491 (2007-11-24)
Food adhesion is an important attribute that could have both positive and negative ramifications depending on the application. Yet, its quantification remains cumbersome and as a consequence adhesion models are scarce. The effect of surface roughness, free energy, and ozone
Elodie Velzenberger et al.
Colloids and surfaces. B, Biointerfaces, 68(2), 238-244 (2008-12-26)
Wettability of biomaterials surfaces and protein-coated substrates is generally characterized with the sessile drop technique using polar and apolar liquids. This procedure is often performed in air, which does not reflect the physiological conditions. In this study, liquid/liquid contact angle

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