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Safety Information

432245

Sigma-Aldrich

Dichlorotetrakis(triphenylphosphine)ruthenium(II)

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About This Item

Linear Formula:
[(C6H5)3P]4RuCl2
CAS Number:
Molecular Weight:
1225.15
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

reaction suitability

core: ruthenium
reagent type: catalyst

SMILES string

Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C18H15P.2ClH.Ru/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;2*1H;/q;;;;;;+2/p-2

InChI key

OIWNHEPSSHYXTG-UHFFFAOYSA-L

Application

Catalyst for:
  • Selective hydrogenation of maleic anhydride or succinic anhydride
  • Sythesis of portions of the natural antibiotic tetrodecamycin
  • Oxidation of hydroxamic acid
  • Hydroesterification reactions
  • Hydroboration of alkenes
  • Oxidation of sulfide

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

432245-VAR:
432245-5G:
432245-BULK:
432245-25G:
432245-1G:


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