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360155

Sigma-Aldrich

Bis(salicylideniminato-3-propyl)methylaminocobalt(II)

97%

Synonym(s):

[[α,α′-[(Methylimino)bis(trimethylenenitrilo)]di-o-cresolato](2-)]cobalt, [[2,2′-[(Methylimino-κN)bis[3,1-propanediyl(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]cobalt

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About This Item

Linear Formula:
CH3N[(CH2)3N=CHC6H4-2-(O)]2Co
CAS Number:
15391-24-9
Molecular Weight:
410.38
MDL number:
MFCD00134174
UNSPSC Code:
12352300
PubChem Substance ID:
24862151
NACRES:
NA.22

Assay

97%

reaction suitability

core: cobalt
reagent type: catalyst

mp

290-292 °C (lit.)

SMILES string

CN1CCC\N=C\c2ccccc2O[Co]Oc3ccccc3\C=N\CCC1

InChI

1S/C21H27N3O2.Co/c1-24(14-6-12-22-16-18-8-2-4-10-20(18)25)15-7-13-23-17-19-9-3-5-11-21(19)26;/h2-5,8-11,16-17,25-26H,6-7,12-15H2,1H3;/q;+2/p-2/b22-16+,23-17+;

InChI key

BJSFADUIUGJFKX-VLQAMQNLSA-L

Application

Catalyst for:
  • Biomimetic coupled catalytic system
  • Cobalt-Schiff base complex catalyzed oxidation of para-substituted phenolics
  • Allylation, oxidation, and oxidative cleavages
  • Oxidative carbonylation of phenol

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

360155-VAR:
360155-5G:
360155-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBZ5413V
MKBQ4712V
08704AU
13916BN

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