Catalyst for C-metal, C-heteroatom and C-C bond formations, addition to unsaturated bonds, cyclizations, functional group transformations, polymerization, oxidations and reductions, carbonylations.
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Cobalt(II) bromide catalyzes arylzincation of alkynes with arylzinc iodide x lithium chloride complexes in acetonitrile. The scope of the arylzincation is wide enough to use unfunctionalized alkynes, such as 6-dodecyne, as well as arylacetylenes. The inherent functional group compatibility of
Efficient cobalt-catalyzed formation of unsymmetrical biaryl compounds and its application in the synthesis of a sartan intermediate.
Muriel Amatore et al.
Angewandte Chemie (International ed. in English), 47(11), 2089-2092 (2008-02-09)
Chemical communications (Cambridge, England), (11), 1474-1475 (2005-03-10)
The intermolecular cyclotrimerisation of terminal and internal alkynes can be catalysed by simple cobalt complexes such as a CoBr2(diimine) under mild reaction conditions when treated with zinc and zinc iodide with high regioselectivity in excellent yields.
Journal of the American Chemical Society, 125(13), 3867-3870 (2003-03-27)
A new chemical method for the preparation of arylzinc intermediates is described in acetonitrile, on the basis of the activation of aryl bromides by low-valent cobalt species arising from the reduction of cobalt halide by zinc dust. This procedure allows
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