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Safety Information

192201

Sigma-Aldrich

2,4,6-Trimethylbenzenesulfonohydrazide

97%

Synonym(s):

2-Mesitylenesulfonohydrazide

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About This Item

Linear Formula:
(CH3)3C6H2SO2NHNH2
CAS Number:
16182-15-3
Molecular Weight:
214.28
Beilstein:
2118380
EC Number:
240-319-4
MDL number:
MFCD00007585
UNSPSC Code:
12352100
PubChem Substance ID:
24851534
NACRES:
NA.22

Assay

97%

mp

112-114 °C (dec.) (lit.)

functional group

hydrazine

SMILES string

Cc1cc(C)c(c(C)c1)S(=O)(=O)NN

InChI

1S/C9H14N2O2S/c1-6-4-7(2)9(8(3)5-6)14(12,13)11-10/h4-5,11H,10H2,1-3H3

InChI key

JQUBKTQDNVZHIY-UHFFFAOYSA-N

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Application

2,4,6-Trimethylbenzenesulfonohydrazide has been used in the synthesis of:
  • (E)-N′-(1-((1S*,4aR*,8aR*)-1-hydroxydecahydronaphthalen-4a-yl)ethylidene)-2,4,6-trimethylbenzenesulfonohydrazide
  • complanadine alkaloids

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H228,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 5: Self-reactive substances
Materials containing Hydrazine derivatives
Hazardous rank I
1st self-reactive materials

JAN Code

192201-25G:
192201-VAR:
192201-BULK:
192201-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
BCBB1327V
BCBB1327
1251849
09813DE
13606CE

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Concise Synthesis of 1, 4a-Bifunctionalised Decalin Building Blocks by CH Activation of Decalin.
Uosis-Martin M, et al.
Synlett, 2011(15), 2211-2213 (2011)
Mario Uosis-Martin et al.
The Journal of organic chemistry, 78(12), 6253-6263 (2013-05-30)
A synthetic approach to complanadine alkaloids is described which employs a Kondrat'eva reaction to construct the pyridine rings. The viability of this approach is demonstrated by its application to a model substrate accessed from unfunctionalized decalin. The key transformation affords

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