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Safety Information

114685

Sigma-Aldrich

4-Nitrophenylhydrazine

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About This Item

Linear Formula:
O2NC6H4NHNH2
CAS Number:
100-16-3
Molecular Weight:
153.14
Beilstein:
608107
EC Number:
202-824-8
MDL number:
MFCD00007579
UNSPSC Code:
12352100
PubChem Substance ID:
329749449

form

solid

contains

≥10% water as stabilizer

mp

156 °C (dec.) (lit.)

SMILES string

NNc1ccc(cc1)[N+]([O-])=O

InChI

1S/C6H7N3O2/c7-8-5-1-3-6(4-2-5)9(10)11/h1-4,8H,7H2

InChI key

KMVPXBDOWDXXEN-UHFFFAOYSA-N

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Pictograms

Exploding BombExclamation mark
GHS01,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Expl. 1.1 - Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

1 - Explosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

114685-1KG:
114685-100G:
114685-25G:
114685-BULK:
114685-VAR:
114685-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
07609MW
02828BW
15923AN
13005PR
06507CN

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I Frébort et al.
European journal of biochemistry, 225(3), 959-965 (1994-11-01)
Interactions of two distinct quinoprotein amine oxidases from Aspergillus niger, AO-I and AO-II, with active-site covalent modifiers have been investigated. Both enzymes are inhibited similarly by phenylhydrazine or p-nitrophenylhydrazine, forming an orange Schiff base with a carbonyl group of topaquinone
V Steinebach et al.
Analytical biochemistry, 230(1), 159-166 (1995-09-01)
Pig kidney diamine oxidase was purified to homogeneity. The reaction product of the cofactor with p-nitrophenylhydrazine (pNPH) was liberated with pronase treatment and purified. 1H NMR, uv/vis, and electrospray tandem mass spectroscopy revealed it to be a dipeptide with the
T Huque et al.
Comparative biochemistry and physiology. B, Comparative biochemistry, 86(1), 135-139 (1987-01-01)
The total plasmalogen content of lingual and other tissues was analyzed using the iodine-addition (Method 1), the p-nitrophenylhydrazone (Method 2), and the two-dimensional thin layer chromatography procedure (Method 3). Methods 1 and 2 were simple, rapid and reproducible, yielding values
Minae Mure et al.
Journal of the American Chemical Society, 125(20), 6113-6125 (2003-06-06)
4-n-Butylamino-5-ethyl-1,2-benzoquinone (1(ox)) has been synthesized as a model compound for the LTQ (lysine tyrosyl quinone) cofactor of lysyl oxidase (LOX). At pH 7, 1(ox) has a lambda(max) at 504 nm and exists as a neutral o-quinone in contrast to a
S R Carter et al.
Journal of inorganic biochemistry, 56(2), 127-141 (1994-11-01)
An improved purification scheme for an amine oxidase from equine plasma (EPAO), a nonruminant source, is described and the protein's active-site is characterized. EPAO is dimeric and contains one Type-2 Cu(II) ion per monomer. The EPAO Cu(II) site is spectroscopically
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