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Merck

Turning on the Protonation-First Pathway for Electrocatalytic CO

Journal of the American Chemical Society (2017-01-25)
Ken T Ngo, Meaghan McKinnon, Bani Mahanti, Remya Narayanan, David C Grills, Mehmed Z Ertem, Jonathan Rochford
ABSTRACT

Electrocatalytic reduction of CO

MATERIALI
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Sigma-Aldrich
Trifluoromethanesulfonic acid, ReagentPlus®, ≥99%
Sigma-Aldrich
Bromopentacarbonylmanganese(I), 98%
Sigma-Aldrich
Tetrabutylammonium trifluoromethanesulfonate, ≥99.0% (T)
Sigma-Aldrich
2,4,6-Trimethylphenylboronic acid, ≥95%
Sigma-Aldrich
6,6′-Dibromo-2,2′-dipyridyl, 90%
Sigma-Aldrich
2,6-Dimethoxyphenylboronic acid, ≥97%
Supelco
Tetrabutylammonium benzoate, for electrochemical analysis, ≥99.0%