675555

1,2-Bis[(2R,5R)-2,5-(dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

• Formula empirica (notazione di Hill): C₂₂H₄₀BF₄P₂Rh
• Numero CAS: 305818-67-1
• Peso molecolare: 556.21
• Codice UNSPSC: 12352005
• ID PubChem: 24885288

Proprietà

• Stato: solid
• Gruppo funzionale: phosphine
• Stringa SMILE: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@@H]2CC[C@@H](C)P2CCP3[C@H](C)CC[C@H]3C
• InChI: 1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m1.../s1; CVUPEPGZCZHSOF-ZTCBNWEGSA-N

Descrizione

Applicazioni

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

• Preparation of substituted phenylalanine via asymmetric hydrogenation of N-acetyldehydroamino acid precursor
• Enantioselective preparation of trifluoromethyl amino acids via asymmetric hydrogenation
• Asymmetric hydrogenation of acetamidocinnamate

Note legali

Sold in collaboration with Kanata Chemical Technologies, Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Informazioni sulla sicurezza

• Pittogrammi: GHS07
• Avvertenze: Warning
• Indicazioni di pericolo: H315,H319,H335
• Consigli di prudenza: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classi di pericolo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: dust mask type N95 (US), Eyeshields, Gloves