36849
Fenoxaprop
PESTANAL®, analytical standard
Synonym(s):
2-{4-[(6-Chlorobenzoxazol-2-yl)oxy]phenoxy}propionic acid
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About This Item
Empirical Formula (Hill Notation):
C16H12ClNO5
CAS Number:
Molecular Weight:
333.72
Beilstein:
8395406
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24
Recommended Products
grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
storage temp.
2-8°C
SMILES string
CC(Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1)C(O)=O
InChI
1S/C16H12ClNO5/c1-9(15(19)20)21-11-3-5-12(6-4-11)22-16-18-13-7-2-10(17)8-14(13)23-16/h2-9H,1H3,(H,19,20)
InChI key
MPPOHAUSNPTFAJ-UHFFFAOYSA-N
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General description
Fenoxaprop is the chiral metabolite formed due to the degradation of its parent compound – Fenoxaprop-ethyl, in soil. Fenoxaprop belongs to the group of aryloxyphenoxypropionate (APP) herbicides and has been used widely for the selective postemergence control of annual and perennial grass weeds in broadleaf crops. This systemic herbicide is primarily absorbed by leaves, translocated both acropetally and basipetally in the phloem and xylem to roots or rhizomes. Fenoxaprop acts by inhibiting acetyl CoA carboxylase (ACCase) – a key enzyme in lipid biosynthesis and blocks the production of phospholipids used in building new membranes.
According to Commission Regulation (1107/2009), fenoxaprop is not approved for use as a plant protection product in the European Union. However, a default MRL of 0.01 mg/kg is set according to Art 18(1)(b) Reg 396 / 2005.
According to Commission Regulation (1107/2009), fenoxaprop is not approved for use as a plant protection product in the European Union. However, a default MRL of 0.01 mg/kg is set according to Art 18(1)(b) Reg 396 / 2005.
Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support. The analytical standard (Pestanal) can be used to:
- Develop an HPLC method for the determination of fenoxaprop-ethyl and fenoxaprop residues in four soil types using two extraction procedures
- Validate the resistance of fenoxaprop in wild oats in Turkey and investigate cross and multiple resistance patterns of fenoxaprop-resistant wild oat populations
- Investigate the degradation of fenoxaprop-ethyl and fenoxaprop in three soils were under native and sterilized conditions using enantioselective high-performance liquid chromatography (HPLC)
- Determine the effect of soil moisture, temperature, and light intensity on the spray deposition of fenoxaprop and imazamethabenz applied to wild oat plants
- Investigate and quantify the resistance of Japanese foxtail (Alopecurus japonicus) to fenoxaprop and pinoxaden in China and elucidate the basis of resistance to these herbicides
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Susana Meseguer-Lloret et al.
Applied spectroscopy, 70(2), 312-321 (2016-02-24)
Two new chemiluminescence (CL) methods are described for the determination of the herbicide 4-(4-chloro-o-tolyloxy) butyric acid (MCPB). First, a flow injection chemiluminescence (FI-CL) method is proposed. In this method, MCPB is photodegraded with an ultraviolet (UV) lamp and the photoproducts
Shizuka Saito-Shida et al.
Analytical methods : advancing methods and applications, 13(7), 894-902 (2021-01-26)
A reliable multiresidue method was developed for determining multiclass acidic pesticides in cereal grains, legumes, vegetables, and fruits. The target pesticides comprise 75 compounds, including phenoxy acid, sulfonylurea, imidazoline, and triazolopyrimidine herbicides, with acidic dissociation constant (pKa) values of 1.9-5.9.
Mahboob Nemati et al.
Journal of separation science, 43(6), 1119-1127 (2019-12-27)
A stir bar sorptive extraction method coupled with deep eutectic solvent based solidification of floating organic droplets-dispersive liquid-liquid microextraction has been used for the simultaneous derivatization and extraction of some acidic pesticides in tomato samples. In this method, initially the
Giovanni D'Orazio et al.
Journal of chromatography. A, 1623, 461213-461213 (2020-06-09)
In the present study separation of enantiomers of some chiral neutral, basic and weakly acidic analytes was investigated on the chiral stationary phase (CSP) made by covalent immobilization of amylose tris(3-chloro-5-methylphenylcarbamate) onto aminopropylsilanized (APS) silica in nano-liquid chromatography (nano-LC) in
Giovanni D'Orazio et al.
Journal of chromatography. A, 1606, 460425-460425 (2019-09-01)
In the present study separation of enantiomers of some chiral neutral and weakly acidic analytes was investigated on the chiral stationary phase (CSP) made by covalent immobilization of amylose tris(3-chloro-5-methylphenylcarbamate) onto silica in nano-liquid chromatography (nano-LC) and capillary electrochromatography (CEC)
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