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388297

Sigma-Aldrich

Ferrocenium hexafluorophosphate

97%

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About This Item

Empirical Formula (Hill Notation):
C10H10F6FeP
CAS Number:
11077-24-0
Molecular Weight:
331.00
MDL number:
MFCD00192173
UNSPSC Code:
12352300
PubChem Substance ID:
24864219
NACRES:
NA.22
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Quality Level

100

Assay

97%

form

powder

reaction suitability

core: iron
reagent type: catalyst

SMILES string

[Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

InChI

1S/2C5H5.F6P.Fe/c2*1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-5H;;/q;;-1;+1

InChI key

JTRCXNUQIANBAN-UHFFFAOYSA-N

Application

The ferrocenium cation has been used to prepare catalysts for the asymmetric epoxidation of olefins,[1] carbonylations of nitroaromatics,[2] and the isomerization of a strained diene.[3]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBG5199V
SHBG2558V
SHBG4056V
SHBD9118V
SHBC5860V

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A series of mixed-valent (MV) complexes [(FeCp)2(mu-C10H6(BPh)2)]+X ([1+]X; X=I 5, PF6, SbF6, B(C6F5)4) were prepared by oxidation of diboradiferrocene [(FeCp)2(mu-C10H6(BPh)2)] (1) with I 2, AgPF6, and AgSbF6, respectively, and through anion exchange of the I 5(-) salt with [Li(Et2O)x][B(C6F5)4] in
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Redox-active ferrocenyl-terminated dendrimers have been used to build robust and active interfaces in which the inherent properties of the dendrimers are preserved. The procedure is based on the preparation of a polyarylcarboxylate layer through the controlled reduction of aryldiazonium salts
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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