31253

Potassium hexacyanoferrate(III)

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99%

• Synonym(s): Potassium ferricyanide, Red prussiate
• Linear Formula: K₃Fe(CN)₆
• CAS Number: 13746-66-2
• Molecular Weight: 329.24
• EC Number: 237-323-3
• MDL number: MFCD00011392
• UNSPSC Code: 12352302
• PubChem Substance ID: 329753702
• NACRES: NB.24
• Assay: ≥99%
• form: crystalline

Properties

• grade: ACS reagent; puriss. p.a.
• Agency: USP/NF; reag. ISO; reag. Ph. Eur.
• Assay: ≥99%
• form: crystalline
• technique(s): titration: suitable
• impurities: ≤0.02% hexacyanoferrate(II) ([Fe(CN)₆]^4-)
• pH: 6-9 (25 °C, 329 g/L)
• anion traces: chloride (Cl^-): ≤50 mg/kg; sulfate (SO₄^2-): ≤50 mg/kg
• cation traces: Ca: ≤5 mg/kg; Cd: ≤5 mg/kg; Co: ≤50 mg/kg; Cu: ≤10 mg/kg; Na: ≤200 mg/kg; Ni: ≤10 mg/kg; Pb: ≤20 mg/kg; Zn: ≤5 mg/kg
• SMILES string: [K+].[K+].[K+].N#C[Fe-3](C#N)(C#N)(C#N)(C#N)C#N
• InChI: 1S/6CN.Fe.3K/c6*1-2;;;;/q;;;;;;-3;3*+1
• InChI key: MIMJFNVDBPUTPB-UHFFFAOYSA-N

Description

General description

Potassium hexacyanoferrate(III) (Potassium ferricyanide) is an alkali hexacyanoferrate. On heating, it undergoes decomposition to afford yellow-brown hexacyanoiron(III) acid. It can be prepared by the anodic oxidation of K₄[Fe(CN)₆].[1]

Application

Potassium hexacyanoferrate(III) may be employed as an oxidizing agent during the fabrication of glucose conductometric biosensor.[2]

Safety Information

• Pictograms: GHS07,GHS09
• Signal Word: Warning
• Hazard Statements: H319,H411
• Precautionary Statements: P264 - P273 - P280 - P305 + P351 + P338 - P337 + P313 - P391
• Hazard Classifications: Aquatic Chronic 2 - Eye Irrit. 2
• Supplementary Hazards: EUH032
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable