672777

(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

98%

• Synonym(s): (3R-trans)-3,4-Bis(diphenylphosphino)-1-(phenylmethyl)pyrrolidine rhodium complex, catASium^® D(R)Rh
• Empirical Formula (Hill Notation): C₄₃H₄₅BF₄NP₂Rh
• CAS Number: 99143-48-3
• Molecular Weight: 827.48
• MDL number: MFCD05861620
• UNSPSC Code: 12352101
• PubChem Substance ID: 329760529

Properties

• Assay: ≥98% (³¹P-NMR); 98%
• SMILES string: [F-].FB(F)F.C1CC=CCCC=C1.C[Rh+]2[PH]([C@@H]3CN(C[C@H]3[PH]2(c4ccccc4)c5ccccc5)Cc6ccccc6)(c7ccccc7)c8ccccc8
• InChI: 1S/C35H33NP2.C8H12.BF4.Rh/c1-6-16-29(17-7-1)26-36-27-34(37(30-18-8-2-9-19-30)31-20-10-3-11-21-31)35(28-36)38(32-22-12-4-13-23-32)33-24-14-5-15-25-33;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-25,34-35H,26-28H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t34-,35-;;;/m1.../s1
• InChI key: HNTLYZLJAZBMKG-JMVIWXBZSA-N

Description

General description

sold in collaboration with Solvias AG

Application

Essential Elements for Asymmetric Hydrogenations

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

catASium is a registered trademark of Umicore AG & Co. KG

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves