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234958

Sigma-Aldrich

1,4-Butanediol dimethacrylate

95%, contains 200-300 ppm MEHQ as inhibitor

Synonym(s):

BDDMA, Butanediol dimethacrylate, Tetramethylene methacrylate

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About This Item

Linear Formula:
[H2C=C(CH3)CO2CH2CH2-]2
CAS Number:
Molecular Weight:
226.27
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Assay

95%

form

liquid

contains

200-300 ppm MEHQ as inhibitor

refractive index

n20/D 1.456 (lit.)

bp

132-134 °C/4 mmHg (lit.)

density

1.023 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(=C)C(=O)OCCCCOC(=O)C(C)=C

InChI

1S/C12H18O4/c1-9(2)11(13)15-7-5-6-8-16-12(14)10(3)4/h1,3,5-8H2,2,4H3

InChI key

XOJWAAUYNWGQAU-UHFFFAOYSA-N

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Application

  • Formulation and polymerization of foamed 1,4-BDDMA-in-water emulsions.: This study focuses on the formulation and polymerization processes of 1,4-Butanediol dimethacrylate (1,4-BDDMA) in water emulsions, showcasing its potential in creating high-performance polymer foams suitable for various industrial applications (Dabrowski et al., 2020).
  • Methacrylate-based polymer foams with controllable connectivity, pore shape, pore size and polydispersity.: The research delves into creating methacrylate-based polymer foams using 1,4-BDDMA, emphasizing its versatility in producing materials with tailored physical properties, which are crucial for biomedical and industrial uses (Dabrowski et al., 2019).
  • Double Replication of Silica Colloidal Crystal Films.: This paper discusses the replication of silica colloidal crystal films using 1,4-BDDMA, highlighting its efficacy in creating structured materials for advanced technological applications (Russell and Mallouk, 2017).
  • In-situ photocrosslinkable nanohybrid elastomer based on polybutadiene/polyhedral oligomeric silsesquioxane.: This study investigates the development of a nanohybrid elastomer using 1,4-BDDMA, focusing on its applications in medical device adhesives and high-performance polymer synthesis (Mirmohammadi et al., 2016).
  • Effects of dental methacrylates on oxygen consumption and redox status of human pulp cells.: Research highlighting the biocompatibility and potential dental applications of 1,4-BDDMA, demonstrating its impact on human pulp cells, which is critical for dental composite materials (Nocca et al., 2014).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Aude Heloise Bonardi et al.
Macromolecular rapid communications, 40(23), e1900495-e1900495 (2019-10-31)
Photo-induced thermal polymerization upon near-infrared (NIR) light irradiation has been reported in the literature. In this approach, a component able to convert the NIR light into heat must be used in combination with a thermal initiator to initiate the free-radical
Susanna Segerström et al.
European journal of oral sciences, 119(3), 246-252 (2011-05-14)
The aim of this study was to determine water sorption, water solubility, dimensional change caused by water storage, residual monomers, and possible cytotoxic effects of heat-polymerized carbon-graphite fibre-reinforced composites with different fibre loadings based on methyl methacrylate/poly(methyl methacrylate) (MMA/PMMA) and
Susanna Segerström et al.
European journal of oral sciences, 113(5), 422-428 (2005-10-06)
Two matrix resins for fiber composites that remain in a fluid state during storage and handling before polymerization were evaluated. The resin mixtures, based on methyl methacrylate (MMA), were produced with two different cross-linking agent systems: 1,4-butanediol dimethacrylate and ethylene
M Krishna Kumar et al.
Journal of peptide science : an official publication of the European Peptide Society, 8(5), 183-191 (2002-06-05)
A highly solvating copolymer was prepared in high yield by introducing a flexible crosslinker, 1,4-butanedioldimethacrylate, into the polystyrene matrix by a free radical aqueous suspension polymerization. A 2 mol% crosslinked resin showed rigidity and mechanical characteristics comparable to those of
Giuseppina Nocca et al.
European journal of oral sciences, 117(2), 175-181 (2009-03-27)
The polymerization of methacrylic monomers present in dental composite resins never reaches completion and therefore the leakage of residual monomers into the oral cavity and into biological fluids can cause local and systemic adverse effects. This work was carried out

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