Saltar al contenido
Merck
Todas las fotos(2)

Key Documents

View All Documentation

H9903

Sigma-Aldrich

1-(Heptafluorobutyryl)imidazole

BioReagent, suitable for derivatization

Sinónimos:

1-(Perfluorobutyryl)imidazole

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(2)

About This Item

Fórmula empírica (notación de Hill):
C7H3F7N2O
Número de CAS:
32477-35-3
Peso molecular:
264.10
Beilstein/REAXYS Number:
4488026
EC Number:
251-063-8
MDL number:
MFCD00014503
UNSPSC Code:
12352005
PubChem Substance ID:
24895875
NACRES:
NA.32

product line

BioReagent

Quality Level

100

bp

158-163 °C (lit.)

suitability

suitable for derivatization

storage temp.

−20°C

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(=O)n1ccnc1

InChI

1S/C7H3F7N2O/c8-5(9,6(10,11)7(12,13)14)4(17)16-2-1-15-3-16/h1-3H

Inchi Key

MSYHGYDAVLDKCE-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

General description

1-(Heptafluorobutyryl)imidazole, also known as HFBI, is an acylating derivatization reagent. It is a mild amine-group derivatizing agent. HFBI doesn’t produce acidic by-products in reaction, and the unutilized reagent doesn’t damage the chromatographic process. Post derivatization reaction, the HFB (Heptafluorobutyryl) derivatives are analyzed chromatographically.

Application

1-(Heptafluorobutyryl)imidazole is used as a derivatizing agent for analysing Sulphur mustard metabolites. It is suitable to study dispersive derivatization of degradation products.

Biochem/physiol Actions

Mild amine-group derivatizing reagent; non-acidic by-product prevents decomposition and reduces GC column degradation.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Meehir Palit et al.
Journal of chromatography. A, 1218(32), 5393-5400 (2011-07-09)
A new derivatization and extraction technique termed as dispersive derivatization liquid-liquid extraction (DDLLE) speeds up the analysis process by removing the requirement for drying of the sample. The derivatization process takes place at the interface between the analyte containing aqueous
A Fidder et al.
Archives of toxicology, 74(4-5), 207-214 (2000-08-26)
The development of a procedure for retrospective detection and quantitation of exposure to the arsenical dichloro(2-chlorovinyl)arsine (lewisite; L1) has been initiated. Upon incubation of human blood with [14C]L1 (20 nM-0.2 mM) in vitro, more than 90% of the total radioactivity
Y Luo et al.
Journal of chromatography. B, Biomedical applications, 667(2), 344-348 (1995-05-19)
A method for the monitoring of dihydroetorphine hydrochloride, a powerful anaesthetic and analgesic drug, in biological fluids was developed, involving GC-MS with multiple selected-ion monitoring. Dihydroetorphine was extracted from human blood and urine with dichloromethane and then derivatized with N-heptafluorobutyrylimidazole
Zhiyong Nie et al.
Talanta, 85(2), 1154-1159 (2011-07-06)
The N-terminal valine adduct (HETE-Val) in globin is believed to behave as a long-lived biomarker after exposure to sulfur mustard (HD). Development of a highly sensitive method for monitoring HETE-Val, particularly at low HD exposure levels or for retrospective detection
The use of tandem mass spectrometry for the identification and quantitation of tryptolines (tetrahydro-beta-carbolines) in tissue extracts.
J V Johnson et al.
Progress in clinical and biological research, 183, 161-177 (1985-01-01)
Ver todos los artículos relacionados

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico