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Merck

D216305

Sigma-Aldrich

2,2′-Bipyridyl

greener alternative

ReagentPlus®, ≥99%

Sinónimos:

2,2′-Bipyridine, 2,2′-Dipyridine, 2,2′-Dipyridyl

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About This Item

Fórmula empírica (notación de Hill):
C10H8N2
Número de CAS:
Peso molecular:
156.18
Beilstein/REAXYS Number:
113089
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

biological source

synthetic (organic)

Quality Level

product line

ReagentPlus®

assay

≥99%

form

powder or crystals
powder or granules

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

bp

273 °C (lit.)

mp

70-73 °C (lit.)

solubility

ethanol: 100 mg/mL, clear, colorless to faintly yellow

greener alternative category

storage temp.

room temp

SMILES string

c1ccc(nc1)-c2ccccn2

InChI

1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H

InChI key

ROFVEXUMMXZLPA-UHFFFAOYSA-N

Gene Information

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General description

2,2′-Bipyridyl also known as 2,2′-bipyridine, is a symmetrical bipyridine commonly used as a neutral ligand for chelating with metal ions. It is a bidentate ligand which has been employed transition metal catalysis, aluminum initiated polymerization, and various other inorganic syntheses. This compound adheres to the principles of greener chemistry, ensuring catalytic efficiency. Click here for more information

Application

2,2′-Bipyridyl has been used in:
  • the preparation of fluorescent dyes like products 754730, 544981, 804215.
  • the preparation ofcopper(II)-bipyridine-naringenin complex.
  • the preparation of 2,2′-bipyridyl hydrobromide.
  • as a ligand in the greener oxidation of alcohols under aerobic conditions
  • as a complex with CuBR2 in the green synthesis of propargylamines
  • the synthesis of [Ru(bipy)3]Cl2, a common metal complex with usefulphotochemistry often used in photoredox catalysis as a sensitizer

Biochem/physiol Actions

Inhibidor de metaloproteasa; agente quelante del hierro de gran afinidad; puede inhibir enzimas que contengan Fe2+ en concentraciones de 10−8 M.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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pictograms

Skull and crossbones

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

267.8 °F - closed cup

flash_point_c

131 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Los clientes también vieron

Macromolecules, 27, 645-645 (1994)
Solvent-Free A3 and KA2 Coupling Reactions with mol ppm Level Loadings of a Polymer-Supported Copper(II)?Bipyridine Complex for Green Synthesis of Propargylamines
Shuo Yan, et al.
ACS sustainable chemistry & engineering, 7 (10), 9097-9102 (2019)
Bromination of 2,2'-bipyridile.
Zdravkov AB and Khimich NN.
Russ. J. Org. Chem., 42(8), 1200-1202 (2006)
Tetrahedron Letters, 34, 6219-6219 (1993)
Júlio César Conceição Filho et al.
PloS one, 9(9), e107058-e107058 (2014-09-06)
Cancer is the second leading cause of death worldwide and there is epidemiological evidence that demonstrates this tendency is emerging. Naringenin (NGEN) is a trihydroxyflavanone that shows various biological effects such as antioxidant, anticancer, anti-inflammatory, and antiviral activities. It belongs

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