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F408

Sigma-Aldrich

Ferrocene

98%

Sinónimos:

Bis(cyclopentadienyl)iron, Di(cyclopentadienyl)iron

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About This Item

Fórmula lineal:
Fe(C5H5)2
Número de CAS:
102-54-5
Peso molecular:
186.03
Número CE:
203-039-3
Número MDL:
MFCD00001427
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
24894802
NACRES:
NA.22
En este momento no podemos mostrarle ni los precios ni la disponibilidad

presión de vapor

0.03 mmHg ( 40 °C)

Nivel de calidad

100

Ensayo

98%

idoneidad de la reacción

core: iron
reagent type: catalyst

bp

249 °C (lit.)

mp

172-174 °C (lit.)

λmáx.

358 nm

temp. de almacenamiento

2-8°C

cadena SMILES

[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;

Clave InChI

DFRHTHSZMBROSH-UHFFFAOYSA-N

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Aplicación

Ferrocene (dicyclopentadienyliron) can be used:
  • As a scaffold for chiral ligands in asymmetric catalysis.[1]
  • In ferrocene-based electrolytes for dye sensitized solar cells applications.[2]
  • In the synthesis of unsymmetrical ferrocene ligands used as catalysts in cross-coupling, hydrogenation, allylic substitution, hydroformylation and aldol reactions.[3]
  • In the synthesis of two-dimensional hexagonally ordered mesoporous carbon (CMK-5) via chemical vapor deposition method, which is used as a catalyst support in oxidation of methanol.[4]
  • In the synthesis of molecular hybrids of ferrocene and fullerene (Bucky ferrocenes).[5]
  • In the preparation of ferrocenium salt which is used as a mild oxidant.[6]

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation

Órganos de actuación

Liver

Código de clase de almacenamiento

4.1B - Flammable solid hazardous materials

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
STBL3617
SDBB0410
STBL2804
STBL3168
STBL1710

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Lanti Yang et al.
Journal of the American Chemical Society, 134(46), 19199-19206 (2012-11-07)
Adopting supramolecular chemistry for immobilization of proteins is an attractive strategy that entails reversibility and responsiveness to stimuli. The reversible and oriented immobilization and micropatterning of ferrocene-tagged yellow fluorescent proteins (Fc-YFPs) onto β-cyclodextrin (βCD) molecular printboards was characterized using surface
Micheál D Scanlon et al.
Physical chemistry chemical physics : PCCP, 15(8), 2847-2857 (2013-01-23)
Rarely reported low-cost molybdenum boride and carbide microparticles, both of which are available in abundant quantities due to their widespread use in industry, adsorb at aqueous acid-1,2-dichloroethane interfaces and efficiently catalyse the hydrogen evolution reaction in the presence of the
CMK-5 mesoporous carbon synthesized via chemical vapor deposition of ferrocene as catalyst support for methanol oxidation
Lei Z, et al.
The Journal of Physical Chemistry C, 3(112), 722-731 (2008)
Asymmetric catalysis with chiral ferrocene ligands
Dai LX, et al.
Accounts of Chemical Research, 36(9), 659-667 (2003)
The syntheses and catalytic applications of unsymmetrical ferrocene ligands
Atkinson RCJ, et al.
Chemical Society Reviews, 33(33), 313-328 (2004)
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Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. What is the thermal stability of the product ferrocene (F408) and what is the temperature limit for ferrocene before it decomposes into different elements or chemicals?

    1 answer

    1. Decomposition temperature has not been tested for the product ferrocene (F408). Please refer to the following article for more information; J. Phys. Chem. B 2006, 110, 42, 20973–20977. Publication Date:September 29, 2006. https://doi.org/10.1021/jp0636571

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