903973

Thianthrene S-oxide

≥95%

• Sinónimos: Non-fluorinated sulfoxide-based thianthrene reagent, Thianthrene 5-oxide
• Fórmula empírica (notación de Hill): C₁₂H₈OS₂
• Número de CAS: 2362-50-7
• Peso molecular: 232.32
• Número MDL: MFCD01464038
• Código UNSPSC: 12352119
• NACRES: NA.22

Propiedades

• Ensayo: ≥95%
• Formulario: powder
• grupo funcional: sulfoxide; thioether
• temp. de almacenamiento: 2-8°C
• cadena SMILES: [S+]1(c2c(cccc2)Sc3c1cccc3)[O-]
• InChI: 1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H
• Clave InChI: NYVGTLXTOJKHJN-UHFFFAOYSA-N

Descripción

Aplicación

Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.

Otras notas

Site-selective and versatile aromatic C-H functionalization by thianthrenation

Video: Site-selective C-H functionalization by thianthrenation

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Información legal

Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable