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84172

Sigma-Aldrich

Salicylaldoxime

≥98.0% (NT)

Sinónimos:

2-Hydroxybenzaldehyde oxime

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About This Item

Fórmula lineal:
2-(HO)C6H4CH=NOH
Número de CAS:
94-67-7
Peso molecular:
137.14
Beilstein/REAXYS Number:
1859881
EC Number:
202-353-8
MDL number:
MFCD00002120
UNSPSC Code:
12352100
PubChem Substance ID:
57652990
NACRES:
NA.22

Quality Level

200

assay

≥98.0% (NT)

form

crystals

mp

57-59 °C
59-61 °C (lit.)

functional group

amine
oxime

SMILES string

O\N=C\c1ccccc1O

InChI

1S/C7H7NO2/c9-7-4-2-1-3-6(7)5-8-10/h1-5,9-10H/b8-5+

InChI key

ORIHZIZPTZTNCU-VMPITWQZSA-N

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Application


  • Novel uncharged triazole salicylaldoxime derivatives as potential acetylcholinesterase reactivators: This research focuses on the synthesis and evaluation of novel salicylaldoxime derivatives, aimed at reactivating acetylcholinesterase inhibited by nerve agents (MH Baghersad, A Habibi, 2023).

  • Selectivity of Salicylaldoxime and its Derivatives: This study utilizes Density Functional Theory (DFT) to examine the selectivity and effectiveness of salicylaldoxime derivatives in various chemical applications (B Tuzun, 2014).

  • Synthesis and Spectroscopic study of Pd(II)-Salicylaldoxime complexes with amine ligands: This paper presents the synthesis and characterization of new Pd(II) complexes with salicylaldoxime, exploring their potential uses in catalysis and material science (EN Al_Sabawi et al., 2021).

Other Notes

Reagent for the spectrophotometric determination of Cu(II), Fe (III), Mo(VI) and Ni(II); a review

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
BCCM2937
BCCK3369
BCCJ4766
BCCJ5206
BCCG1083

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Ross S Forgan et al.
Dalton transactions (Cambridge, England : 2003), 39(7), 1763-1770 (2010-05-08)
3-Dialkylaminomethyl substituted salicylaldoximes are efficient metal salt extractants, and, in contrast to related "salen"-based reagents, are sufficiently stable to acid hydrolysis to allow commercial application in base metal recovery. Crystal structures show that metal salts are bound by a zwitterionic
Anna Tobiasz et al.
Talanta, 96, 82-88 (2012-07-24)
The paper presents application of a new resin dedicated to copper(II) flow-injection on-line preconcentration prior its flame atomic absorption spectrometric (FAAS) determination. The new sorbent, obtained by suspension polymerization technique, was styrene-divinylbenzene copolymer modified with 5-dodecylsalicylaldoxime-copper(II) complex. In flow mode
Tiziano Tuccinardi et al.
Bioorganic & medicinal chemistry, 21(6), 1511-1515 (2012-09-29)
New compounds containing a novel zinc binding group (salicylaldoxime system) were identified as effective inhibitors of carbonic anhydrases (CAs). This structural motif seems to bind the catalytic zinc ion of CAs, revealing itself as a new valid alternative to the
Peter A Wood et al.
Acta crystallographica. Section B, Structural science, 62(Pt 6), 1099-1111 (2006-11-17)
The effect of pressure on the crystal structure of salicylaldoxime has been investigated. The ambient-pressure phase (salicylaldoxime-I) consists of pairs of molecules interacting through oximic OH...O hydrogen bonds; taken with phenolic OH...N intramolecular hydrogen bonds, these dimers form a pseudo-macrocycle
Constantinos J Milios et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 1809-1817 (2008-03-29)
The use of derivatised salicylaldoximes in Mn chemistry has led to the isolation of a plethora of beautiful new SMMs ranging in nuclearity from three to eight and with spin ground states as large as S = 12-including a Mn6
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