798320

2-Bromo-6-(trimethylsilyl)phenyl triflate

95%

• Sinónimos: Garg 3-Bromobenzyne Precursor
• Fórmula empírica (notación de Hill): C₁₀H₁₂BrF₃O₃SSi
• Número de CAS: 1092542-31-8
• Peso molecular: 377.25
• UNSPSC Code: 12352100
• PubChem Substance ID: 329768639
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: 95%
• form: liquid
• refractive index: n/D 1.492
• density: 1.482 g/L at 25 °C
• functional group: bromo; fluoro; triflate
• storage temp.: 2-8°C
• SMILES string: O=S(OC1=C([Si](C)(C)C)C=CC=C1Br)(C(F)(F)F)=O
• InChI: 1S/C10H12BrF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3
• InChI key: ZNKAHJCGEPVEBA-UHFFFAOYSA-N

Descripción

Application

Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes

Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors

Bromosilyltriflate has been shown to be a useful precursor for the generation of a bromobenzyne intermediate. The bromobenzyne intermediate can be generated in the presence of cesium or potassium fluoride and can be trapped with various dipolariphiles.

Información de seguridad

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable