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745480

Sigma-Aldrich

Zinc isopropylsulfinate

95%

Sinónimos:

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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About This Item

Fórmula empírica (notación de Hill):
C6H14O4S2Zn
Número de CAS:
1416821-55-0
Peso molecular:
279.69
MDL number:
MFCD24386390
UNSPSC Code:
12352001
PubChem Substance ID:
329764984
NACRES:
NA.22

Quality Level

100

assay

95%

form

solid

reaction suitability

reaction type: Allylation
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

mp

161-166 °C

SMILES string

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

InChI key

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Linkage

Frequently Asked Questions are available for this Product.

Preparation Note

may contain up to 1 mole eq ZnCl2

Other Notes

Previously sold under product number L511161

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCN1076
MKCJ2637
MKCD0333
MKCB0914V
MKBX5822V

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Meiqi Niu et al.
eLife, 9 (2020-07-03)
The intraparietal sulcus (IPS) is structurally and functionally heterogeneous. We performed a quantitative cyto-/myelo- and receptor architectonical analysis to provide a multimodal map of the macaque IPS. We identified 17 cortical areas, including novel areas PEipe, PEipi (external and internal
Bonnie Bailet et al.
The Science of the total environment, 745, 140948-140948 (2020-08-01)
Ecological assessment of lakes and rivers using benthic diatom assemblages currently requires considerable taxonomic expertise to identify species using light microscopy. This traditional approach is also time-consuming. Diatom metabarcoding is a promising alternative and there is increasing interest in using
Jasmine Siew Min Chia et al.
Frontiers in pharmacology, 11, 92-92 (2020-03-21)
Zerumbone has shown great potential in various pathophysiological models of diseases, particularly in neuropathic pain conditions. Further understanding the mechanisms of action is important to develop zerumbone as a potential anti-nociceptive agent. Numerous receptors and pathways function to inhibit and
Chun You et al.
Biotechnology and bioengineering, 114(8), 1855-1864 (2017-04-15)
Myo-Inositol (vitamin B8) is widely used in the drug, cosmetic, and food & feed industries. Here, we present an in vitro non-fermentative enzymatic pathway that converts starch to inositol in one vessel. This in vitro pathway is comprised of four
Rie Poulsen et al.
Trials, 18(1), 578-578 (2017-12-05)
Depression and anxiety are among the largest contributors to the global burden of disease and have negative effects on both the individual and society. Depression and anxiety are very likely to influence the individual's work ability, and up to 40%
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