637998

Vinylboronic anhydride pyridine complex

95%

• Sinónimos: 2,4,6-Trivinylcyclotriboroxane pyridine complex, Trivinyl-boroxin pyridine complex, Trivinylcyclotriboroxane pyridine complex
• Fórmula empírica (notación de Hill): C₆H₉B₃O₃ · C₅H₅N
• Número de CAS: 442850-89-7
• Peso molecular: 240.67
• Número MDL: MFCD03839940
• Código UNSPSC: 12352103
• ID de la sustancia en PubChem: 24882902
• NACRES: NA.22

Propiedades

• Nivel de calidad: 100
• Ensayo: 95%
• Formulario: solid
• temp. de almacenamiento: −20°C
• cadena SMILES: c1ccncc1.C=Cb2ob(C=C)ob(C=C)o2
• InChI: 1S/C6H9B3O3.C5H5N/c1-4-7-10-8(5-2)12-9(6-3)11-7;1-2-4-6-5-3-1/h4-6H,1-3H2;1-5H
• Clave InChI: YLHJACXHRQQNQR-UHFFFAOYSA-N

Descripción

Aplicación

Reagent used for

• Suzuki-Miyaura cross-coupling
• Stereoselective synthesis via Palladium-catalyzed carboamination
• Alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent to cytosine base in RNA
• Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media
• Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers
• Stereoselective isomerization of N-allyl aziridines into Z-enamines by using rhodium hydride catalysis
• Kinetic resolution of axially chiral biaryl derivatives via palladium/chiral diamine ligand-catalyzed alcoholysis
• Transition metal-catalyzed alkenylation of aziridines, cycloaddition and thermal rearrangement reactions
• Intramolecular Heck reaction strategy for synthesis of functionalized tetrahydroanthracenes

Reagent used for Preparation of

• BACE-1 inhibitors and SAR of cyclic sulfone hydroxyethylamines
• Distorted spiropentanes
• Small molecule bradykinin B2 receptor antagonists in angioedema therapy
• Enol Ethers
• Styryl cyclobutanone

Información de seguridad

• Pictogramas: GHS07
• Palabra de señalización: Warning
• Frases de peligro: H319
• Consejos de prudencia: P305 + P351 + P338
• Clasificaciones de peligro: Eye Irrit. 2
• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): 176.0 °F - closed cup
• Punto de inflamabilidad (°C): 80 °C - closed cup
• Equipo de protección personal: dust mask type N95 (US), Eyeshields, Gloves