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Merck

522376

Sigma-Aldrich

Poly(diallyldimethylammonium chloride) solution

average Mw <100,000 (very low molecular weight), 35 wt. % in H2O

Sinónimos:

PDADMAC

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About This Item

Fórmula lineal:
(C8H16ClN)n
Número de CAS:
MDL number:
UNSPSC Code:
12162002
NACRES:
NA.23

mol wt

average Mw <100,000 (very low molecular weight)

Quality Level

concentration

35 wt. % in H2O

refractive index

n20/D 1.417

viscosity

100-200 cP(25 °C)

density

1.09 g/mL at 25 °C

InChI

1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1

InChI key

GQOKIYDTHHZSCJ-UHFFFAOYSA-M

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General description

Poly(diallyldimethylammonium chloride) (PDDA) is a cationicpolyelectrolyte that easily ionizes when dissolved in water. This polymer iswidely used in the fields of waste-water treatment (as a flocculant) and the functionalizationof nanoparticles.

Application

Poly(diallyldimethylammonium chloride) can be used as a stabilizing agent in the synthesis of nanoparticles such as capped copper hexacyanoferrate (CuHCF) nanoparticles. The addition of PDDA protects the particles from aggregation and allows the synthesis of nanoparticles with controlled size and polydispersity. It can also be used to fabricate chemical and biological sensors. For example, PDDA-modified catalyst platforms can be used in the electrochemical detection of L-cysteine.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

>212.0 °F - closed cup

flash_point_c

> 100 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Synthesis of poly(diallyldimethylammonium) capped copper hexacyanoferrate (CuHCF) nanoparticles: An efficient stabiliser for Pickering emulsions
Martin Mayer, et al.
Journal of Colloid and Interface Science, 505, 364-372 (2017)
The p-type MoS2 nanocube modified poly(diallyl dimethyl ammonium chloride)-mesoporous carbon composites as a catalytic amplification platform for electrochemical detection of l-cysteine
Zhixiang Zheng, et al.
Sensors and Actuators B, Chemical, 221, 1162-1169 (2015)
Shangzhi Chen et al.
Nature nanotechnology, 15(1), 35-40 (2019-12-11)
Being able to dynamically shape light at the nanoscale is one of the ultimate goals in nano-optics1. Resonant light-matter interaction can be achieved using conventional plasmonics based on metal nanostructures, but their tunability is highly limited due to a fixed
Cédric Amorosi et al.
Colloids and surfaces. B, Biointerfaces, 97, 124-131 (2012-05-23)
Compact and linearly growing polyelectrolyte multilayer films have been used to suppress desorption of drugs, nanoparticles or proteins from underlying polyelectrolyte multilayer films as well as to significantly change their mechanical properties. The polyelectrolyte based capping layers are however cumbersome
John Crosby et al.
Chemical communications (Cambridge, England), 48(97), 11832-11834 (2012-10-27)
Compartmentalization of the minimal complex of actinorhodin polyketide synthase in coacervate liquid droplets produces enhanced yields of shunt polyketides under conditions of low and high ionic strength.

Artículos

Recently, layer-by-layer (LbL) assembly has emerged as a versatile, gentle and, simple method for immobilization of functional molecules in an easily controllable thin film morphology.1,2 In this short review, we introduce recent advances in functional systems fabricated by using the mild, yet adaptable LbL technique.

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

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