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Merck

450162

Sigma-Aldrich

Potassium hexachloroiridate(IV)

99.99% trace metals basis

Sinónimos:

Iridium potassium chloride

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About This Item

Fórmula lineal:
K2IrCl6
Número de CAS:
Peso molecular:
483.13
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.99% trace metals basis

form

powder

impurities

≤150.0 ppm Trace Metal Analysis

mp

>385 °C (lit.)

SMILES string

[K+].[K+].Cl[Ir--](Cl)(Cl)(Cl)(Cl)Cl

InChI

1S/6ClH.Ir.2K/h6*1H;;;/q;;;;;;+4;2*+1/p-6

InChI key

WEKZJZDULNNSCD-UHFFFAOYSA-H

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Application

  • Voltammetry at HMT-PMBI-coated glassy carbon electrodes: This study explores the electrochemical properties of potassium hexachloroiridate(IV) and its potential for sensitive detection, which could be valuable in analytical chemistry applications (M Rees et al., 2020).
  • Antioxidant Total Capacity Assay: Introduces a novel assaying method for antioxidant capacity using potassium hexachloroiridate(IV), which could have implications in pharmacology and drug discovery (Y Liu et al., 2024).
  • Mass Transfer in 3D-printed Electrolyzers: Examines the role of potassium hexachloroiridate(IV) in enhancing mass transfer in electrolytic systems, which is pivotal for chemical engineering and energy applications (SJC Weusten et al., 2021).

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Z S Farhangrazi et al.
Biochemistry, 34(46), 14970-14974 (1995-11-21)
Horseradish peroxidase (HRP) was oxidized by IrCl6(2-) to a mixture of compounds I and II, the rate of oxidation and the ratio of the mixture being greatly affected by pH (Hayashi & Yamazaki, 1979). Oxidation of HRP by IrCl6(2-) in
Na Song et al.
Inorganic chemistry, 47(24), 11458-11460 (2008-11-14)
One-electron oxidation of phenol, 2,4,6-trimethylphenol, and 2,6-dimethylphenol by [IrCl(6)](2-) in aqueous solution has a simple pH dependence, indicating slow bimolecular oxidation of ArOH and faster oxidation of ArO(-). H/D kinetic isotope effects as large as 3.5 for oxidation of ArOH
Fabrizio Testa et al.
Free radical biology & medicine, 51(8), 1567-1574 (2011-08-16)
Unlike superoxide dismutases (SODs), superoxide reductases (SORs) eliminate superoxide anion (O(2)(•-)) not through its dismutation, but via reduction to hydrogen peroxide (H(2)O(2)) in the presence of an electron donor. The microaerobic protist Giardia intestinalis, responsible for a common intestinal disease
Olga Kornyushyna et al.
Biochemistry, 41(51), 15304-15314 (2002-12-18)
The low redox potential of 8-oxo-7,8-dihydroguanine (OG), a molecule regarded as a marker of oxidative damage in cells, makes it an easy target for further oxidation. Using a temperature-dependent method of synthesis, the oxidation products of OG, guanidinohydantoin (Gh) and/or
Y Kaneko et al.
Biochemistry, 19(25), 5795-5799 (1980-12-09)
Zinc-substituted horseradish peroxidase is oxidized by K2IrCl6 to a characteristic state which retains one oxidizing equivalent more than the zinc peroxidase. The oxidized enzyme gives an optical absorption spectrum similar to that of compound I of peroxidase and catalase, and

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