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Merck

43961

Sigma-Aldrich

1-Allyl-3-methylimidazolium chloride

greener alternative

≥97.0% (HPLC)

Sinónimos:

AMIM-Cl

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About This Item

Fórmula empírica (notación de Hill):
C7H11ClN2
Número de CAS:
Peso molecular:
158.63
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥97.0% (HPLC)

form

crystals

greener alternative product characteristics

Safer Solvents and Auxiliaries
Catalysis
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sustainability

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storage temp.

−20°C

SMILES string

[Cl-].C[n+]1ccn(CC=C)c1

InChI

1S/C7H11N2.ClH/c1-3-4-9-6-5-8(2)7-9;/h3,5-7H,1,4H2,2H3;1H/q+1;/p-1

InChI key

QVRCRKLLQYOIKY-UHFFFAOYSA-M

General description

1-Allyl-3-methylimidazolium chloride is a thermostable and nonvolatile task-specific ionic liquid (TSIL). It shows high cellulose solubilization ability.
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Application

AMIM-Cl may be used:
  • As a solvent to dissolve cellulose during the preparation of regenerated cellulose materials.
  • As a solvent for the acetylation of cornhusk cellulose to form cornhusk cellulose acetates (CCAs).
  • As a plasticizer for cornstarch to form AMIM-Cl-plasticized starch film.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificados de análisis (COA)

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Visite la Librería de documentos

Ganeswar Sahu et al.
Polymers, 12(2) (2020-02-13)
This paper presents the dielectric characteristics of nanocomposite films of poly(vinyl alcohol) (PVA) embedded with silver (Ag) nanoparticles and graphene oxide(GO). The nanocomposite films were fabricated by using the solvent casting approach. The morphological analysis was carried out through scanning
Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl).
Cao Y, et al.
Carbohydrate Polymers, 69(4), 665-672 (2007)
Ashna Rajeev et al.
Soft matter, 14(37), 7615-7624 (2018-08-31)
Water added to a solution of microcrystalline cellulose (MCC) in 1-allyl-3-methylimidazolium chloride (AmimCl) reduces the solvent quality and causes significant changes in the flow properties and microstructure due to restructuring and aggregation of cellulose molecules. We report an experimental investigation
Tosylation and acylation of cellulose in 1-allyl-3-methylimidazolium chloride.
Granstrom M, et al.
Cellulose, 15(3), 481-488 (2008)
1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: a new and powerful nonderivatizing solvent for cellulose.
Zhang H, et al.
Macromolecules, 38(20), 8272-8277 (2005)

Artículos

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

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