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Key Documents

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394912

Supelco

Heptafluorobutyric anhydride

for GC derivatization, LiChropur™, ≥99.0%

Sinónimos:

HFBA, HFAA, Perfluorobutyric anhydride

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About This Item

Fórmula lineal:
(CF3CF2CF2CO)2O
Número de CAS:
336-59-4
Peso molecular:
410.06
Beilstein/REAXYS Number:
856036
EC Number:
206-410-8
MDL number:
MFCD00000432
UNSPSC Code:
12000000
PubChem Substance ID:
24864629
NACRES:
NA.22

grade

for GC derivatization

Quality Level

100

assay

≥99.0%

form

liquid

quality

LiChropur™

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.287 (lit.)

bp

108-110 °C (lit.)

mp

−43 °C (lit.)

density

1.674 g/mL at 20 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C8F14O3/c9-3(10,5(13,14)7(17,18)19)1(23)25-2(24)4(11,12)6(15,16)8(20,21)22

InChI key

UFFSXJKVKBQEHC-UHFFFAOYSA-N

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General description

Heptafluorobutyric anhydride (HFB) is a derivatizing reagent. It provides facile and sensitive way for detecting and elucidating structure of numerous alkyl-chain homologs.

Application

Learn more in the Product Information
GC derivatizing agent used to prepare volatile derivatives of amino acids and other biologically active compounds.
HFB was used as derivatizing agent in analysing platelet-activating factor using GC-MS.
Suitable for the derivatization of aldosterone, digoxin, digitoxin and metabolites, estradiol, postaglandins F1α and F2α, 3-oxo-Δ4-steroids, and testosterone.

Packaging

Derivatization reagent used in a GC-MS analysis of stereoisomer content of synthetic peptides.

Other Notes

Reagent for heptafluorobutyrate, 3-enol heptafluorobutyrate, 17-heptafluorobutyrate, heptafluorobutyrate and heptafluorobutyryl.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

For use with

Referencia del producto
Descripción
Precios

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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J Bakthavachalam et al.
Journal of chromatography, 500, 373-386 (1990-02-02)
Several electrophoric derivatives of 1-aminopyrene and 2-aminofluorene were prepared. Reagents such as heptafluorobutyryl chloride, pentafluorobenzoyl chloride, pentafluorobenzyl bromide and pentafluorobenzaldehyde, alone and in certain combinations, were employed. The ease of formation, yield, stability and fragmentation by gas chromatography with electron-capture
S T Weintraub et al.
Journal of lipid research, 31(4), 719-725 (1990-04-01)
Parallel analysis of platelet-activating factor (PAF) using chemical ionization gas chromatography-mass spectrometry after direct derivatization with pentafluorobenzoyl chloride (PFB) and heptafluorobutyric anhydride (HFB) provides a facile and highly sensitive means for detecting and elucidating the structure of the numerous alkyl-chain
Ralf Pätzold et al.
Chirality, 18(7), 551-557 (2006-05-10)
Synthetic dipeptides comprising mixtures of enantiomers, diastereomers, or sequential isomers were converted into their N-perfluoroacetyl dipeptide esters (perfluoroacetyl: trifluoroacetyl, pentafluoroacetyl, heptafluorobutyryl; ester: methyl, 1-propyl, 2-propyl, 2,2,2-trifluoroethyl) and analyzed by GC-MS on the chiral stationary phases Chirasil-L-Val and Lipodex-E using helium
Ronald Agius et al.
Forensic science international, 196(1-3), 3-9 (2010-01-12)
The analysis of ethyl glucuronide (EtG) in hair is a powerful tool for chronic alcohol abuse control because of the typical wide detection window of the hair matrix and due to the possibility of segmentation, allowing evaluation of alcohol consumption
O Beck et al.
Journal of analytical toxicology, 22(1), 45-49 (1998-03-10)
The use of mushrooms containing the hallucinogenic substance psilocybin for intentional intoxication is relatively common. Occasionally, this results in adverse reactions with typical tachycardia that is not evidently caused by psilocybin. This study demonstrates the presence of phenylethylamine in the
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