373567

Ruthenium(III) nitrosyl nitrate solution

in dilute nitric acid

• Sinónimos: Nitrilooxonium ruthenium(2+) nitrate (1:1:3)
• Fórmula lineal: Ru(NO)(NO₃)_x(OH)_y, x+y=3
• Número de CAS: 34513-98-9
• Peso molecular: 318.10
• MDL number: MFCD00016313
• UNSPSC Code: 12352302
• PubChem Substance ID: 24863244
• NACRES: NA.23

Propiedades

• form: liquid
• Quality Level: 100
• composition: Ru, 1.5% (typical)
• reaction suitability: reagent type: catalyst; core: ruthenium
• concentration: in dilute nitric acid
• density: 1.07 g/mL at 25 °C
• SMILES string: [Ru+3]N=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/3NO3.NO.Ru/c3*2-1(3)4;1-2;/q4*-1;+4
• InChI key: VAAILMLOAHTPQK-UHFFFAOYSA-N

Descripción

General description

Ruthenium(III) nitrosyl nitrate solution is a stable and water-soluble compound. The presence of the nitrosyl ligand contributes to its distinct reactivity and coordination behavior. Additionally, the compound exhibits characteristic spectroscopic properties that make it valuable in analytical and research applications.

Application

Ruthenium(III) nitrosyl nitrate solution can be used:

• As a Ru source to prepare Y₂Ru₂O₇/NiMoO₄@NF electrocatalyst by a combined sol–gel and hydrothermal method, which exhibits superior stability for overall water splitting in an alkaline medium.
• To fabricate bifunctional electrode for Li-air batteries.
• As a precursor to synthesize ruthenium nanoparticles with variable sizes. It helps to form stable ruthenium nitrite complex avoiding the unwanted metal oxide hydrolysis or precipitation.

Información de seguridad

• pictograms: GHS05,GHS07
• signalword: Danger
• hcodes: H290,H314,H332
• pcodes: P234 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A
• supp_hazards: EUH071
• Storage Class: 8B - Non-combustible corrosive hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter