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230499

Sigma-Aldrich

Selenourea

98%

Sinónimos:

2-Selenourea, Carbamimidoselenoic acid, Isoselenourea, Selenouronium

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About This Item

Fórmula lineal:
NH2CSeNH2
Número de CAS:
630-10-4
Peso molecular:
123.02
Beilstein:
1734744
Número CE:
211-129-9
Número MDL:
MFCD00008065
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
24853808
NACRES:
NA.22
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Nivel de calidad

100

Ensayo

98%

Formulario

solid

mp

210-215 °C (dec.)

grupo funcional

amine

cadena SMILES

NC(N)=[Se]

InChI

1S/CH4N2Se/c2-1(3)4/h(H4,2,3,4)

Clave InChI

IYKVLICPFCEZOF-UHFFFAOYSA-N

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Aplicación

Selenourea [(SeC(NH2)2)] has been used as a selenium (Se) precursor for the insertion of Se into protein crystals.[1]
It can also be used as a reagent to synthesize:
  • Selenazoles from α -bromo ketones presence of β -cyclodextrin.[2]
  • Symmetrical diaryl selenides by C-Se cross coupling reaction in presence of coper oxide nanaoparticles as a catalyst.[3]
  • CdSe nanocrystals.[4]

Palabra de señalización

Danger

Frases de peligro

H300,H331,H373,H410

Clasificaciones de peligro

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
BCCL9168
BCCK4577
BCCJ5328
BCCG5429
BCCF7366

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Sung Min Kwon et al.
Science advances, 4(4), eaap9104-eaap9104 (2018-04-18)
We report a general strategy for obtaining high-quality, large-area metal-chalcogenide semiconductor films from precursors combining chelated metal salts with chalcoureas or chalcoamides. Using conventional organic solvents, such precursors enable the expeditious formation of chalco-gels, which are easily transformed into the
A novel synthesis of CdSe nanocrystals
Epifani M, et al.
Materials Letters, 58(19), 2429-2432 (2004)
M Narender et al.
The Journal of organic chemistry, 72(5), 1849-1851 (2007-02-03)
Selenazoles were synthesized from alpha-bromo ketones and selenourea in the presence of beta-cyclodextrin in water at 50 degrees C under atmospheric pressure.
V Prakash Reddy et al.
The Journal of organic chemistry, 75(24), 8720-8723 (2010-11-26)
Selenourea is used as an effective selenium surrogate in the C-Se cross-coupling reaction catalyzed by copper oxide nanoparticles under ligand free conditions. This protocol has been utilized for the synthesis of a variety of symmetrical diaryl selenides in good to
Milind Devidas Deore et al.
Veterinary and human toxicology, 44(5), 260-263 (2002-10-04)
Selenium (SC) toxicity was experimentally induced in male buffalo calves following repeated oral administration of 0.3 mg selenourea/kg (providing 0.19 mg/Se kg) for 75 d. On the basis of the major toxic effects produced in the experimental animals, 10 additional
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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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