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208523

Sigma-Aldrich

Ruthenium(III) chloride

Ru content 45-55%

Sinónimos:

Ruthenium trichloride

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About This Item

Fórmula lineal:
RuCl3
Número de CAS:
10049-08-8
Peso molecular:
207.43
Número CE:
233-167-5
Número MDL:
MFCD00011208
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
24852520
NACRES:
NA.22

Formulario

solid

idoneidad de la reacción

core: ruthenium
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

densidad

3.11 g/mL at 25 °C (lit.)

cadena SMILES

Cl[Ru](Cl)Cl

InChI

1S/3ClH.Ru/h3*1H;/q;;;+3/p-3

Clave InChI

YBCAZPLXEGKKFM-UHFFFAOYSA-K

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Descripción general

Ruthenium(III) chloride is a chemical compound, that can be used as a mild Lewis acid catalyst for the acetalization of aldehydes, acetalization of alcohols, and conversion of ketoximes to amides. Additionally, it can also be used as a precursor to synthesize Ru nanoparticles.

Aplicación

Ruthenium(III) chloride is used as a catalyst:

  • In the synthesis of β‐amino alcohols by nucleophilic opening of epoxides with anilines.
  • In the acetylation of varies of phenols, alcohols, thiols, and amines under mild conditions.
  • In the synthesis of α‐aminonitriles by mixing aldehydes, amines, and trimethylsilyl cyanides.

Otras notas

insoluble form

Palabra de señalización

Danger

Frases de peligro

H302,H314,H411

Clasificaciones de peligro

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Código de clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
MKCW7012
MKCV8944
MKCV8943
0000275087
0000229689

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Sébastien Perdriau et al.
ChemSusChem, 5(12), 2427-2434 (2012-10-13)
Cardanol, a constituent of cashew nutshell liquid (CNSL), was subjected to transfer hydrogenation catalyzed by RuCl(3) using isopropanol as a reductant. The side chain of cardanol, which is a mixture of a triene, a diene, and a monoene, was selectively
Shū Kobayashi et al.
Organic letters, 4(8), 1319-1322 (2002-04-13)
Several transition metal salts were found to catalyze aza-Michael reactions of enones with carbamates efficiently. The catalytic activity was strongly dependent on the nature of the metal salts. While conventional Lewis acids such as BF(3).OEt(2), AlCl(3), or TiCl(4) showed lower
Wanqing Teng et al.
Frontiers in chemistry, 8, 334-334 (2020-05-21)
It is highly promising to design and develop efficient and economical electrocatalysts for oxygen evolution reaction (OER) in alkaline solution. In this work, we prepare FeCoNi sulfide composites (including FeS, Co3S4, and Ni3S4) derived from in situ sulfurization of precursor
Ruthenium (III) chloride catalyzed acylation of alcohols, phenols, thiols, and amines
De SK
Tetrahedron Letters, 45(14), 2919-2922 (2004)
Hitoshi Harada et al.
The Journal of organic chemistry, 73(17), 6772-6779 (2008-08-07)
Highly enantioselective catalytic intramolecular ortho-alkylation of aromatic imines containing alkenyl groups tethered at the meta position relative to the imine directing group has been achieved using [RhCl(coe)2]2 and chiral phosphoramidite ligands. Cyclization of substrates containing 1,1- and 1,2-disubstituted as well
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