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Merck

128252

Sigma-Aldrich

Ethylene sulfide

98%

Sinónimos:

Dimethylene sulfide, Thiirane

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About This Item

Fórmula empírica (notación de Hill):
C2H4S
Número de CAS:
Peso molecular:
60.12
Beilstein/REAXYS Number:
102379
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

4.15 psi ( 20 °C)

assay

98%

form

liquid

contains

0.5-1.4% n-butyl mercaptan as stabilizer

refractive index

n20/D 1.495 (lit.)

bp

55-56 °C (lit.)

density

1.01 g/mL at 25 °C (lit.)

functional group

thioether

storage temp.

−20°C

SMILES string

C1CS1

InChI

1S/C2H4S/c1-2-3-1/h1-2H2

InChI key

VOVUARRWDCVURC-UHFFFAOYSA-N

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Application

  • Ethylene sulfide is generally used in the preparation of organosulfur compounds, especially for mercaptoethylation of primary and secondary amines to obtain aminothiols.
  • It is used in the synthesis of dendritic thioether ligands to stabilize gold nanoparticles (Au NPs).
  • Chitosan can be chemically modified by treating ethylene sulfide to obtain a biopolymer for the removal of divalent cations from aqueous solutions.

Ethylene sulfide was used in the chemical modificatoion of biopolymer chitosan.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

50.0 °F - closed cup

flash_point_c

10 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves


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Los clientes también vieron

Gold nanoparticles stabilized by thioether dendrimers.
Hermes J P, et al.
Chemistry?A European Journal , 17(48), 13473-13481 (2011)
W C Stolte et al.
The Journal of chemical physics, 133(1), 014306-014306 (2010-07-10)
We have investigated the photofragmentation properties of the three-membered ring heterocyclic molecule ethylene sulfide or thiirane, C(2)H(4)S, by time-of-flight mass spectroscopy. Positive ions have been collected as a function of photon energy around the S K ionization threshold. Branching ratios
Adriana P Vieira et al.
International journal of biological macromolecules, 52, 107-115 (2012-09-27)
The biopolymer chitosan was chemically modified in two sequences of reactions: (i) immobilization of methyl acrylate followed by cysteamine and (ii) the sequence of immobilization reactions involving ethylene sulfide, methyl acrylate and finally cysteamine. In both cases the pendant chains
Ethylene Sulfide.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2010)
Evangelina Repetto et al.
The Journal of organic chemistry, 77(1), 253-265 (2011-11-19)
Satisfactory procedures are described for the synthesis of 5,6- and 3,4-thiirane derivatives from the respective hexofuranose or hexopyranose epoxide precursors. The controlled ring-opening reaction of thiiranes by 1-thioaldoses was successfully accomplished to afford, regio- and stereoselectively, β-S-(1→4)-3,4-dithiodisaccharides. For instance, the

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