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Merck

215465

Sigma-Aldrich

氯化汞(II)

ACS reagent, ≥99.5%

别名:

二氯化汞

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About This Item

线性分子式:
HgCl2
CAS号:
分子量:
271.50
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent

蒸汽壓力

1.3 mmHg ( 236 °C)

化驗

≥99.5%

形狀

powder

反應適用性

reagent type: catalyst
core: mercury

還原殘基

≤0.02%

mp

277 °C (lit.)

溶解度

acetic acid: soluble(lit.)
acetone: soluble in salt form(lit.)
alcohol: soluble(lit.)
diethyl ether: passes test
ethyl acetate: soluble(lit.)
glycerol: soluble(lit.)
water: soluble(lit.)

正離子痕跡

Fe: ≤0.002%

SMILES 字串

Cl[Hg]Cl

InChI

1S/2ClH.Hg/h2*1H;/q;;+2/p-2

InChI 密鑰

LWJROJCJINYWOX-UHFFFAOYSA-L

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一般說明

Mercury (II) chloride is an inorganic salt commonly used as a catalyst in organic synthesis.

應用

Mercury (II) chloride can be used as a catalyst for the:
  • Addition reaction between aromatic amines to terminal acetylenes to give imines, enamines, and 1,2,3,4-tetrahydroquinoline derivatives.
  • Cyclization of amidinothioureas with phenyl hydrazine to produce 3-amino-1,2,4-triazole derivatives.
  • Cyclization of O-propargyl glycolaldehyde dithioacetals to afford 3-pyranones along with 2,5-dihydrofuran-3-carboxaldehydes through their dithioketals and dithioacetals reaction.
  • Reductive dimerization and cyclization of α,β-unsaturated ketones produce functionalized cyclopentanols using N,N-dimethylformamide as solvent.

訊號詞

Danger

危險分類

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 1

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Ashley E Peppriell et al.
Toxicology, 443, 152561-152561 (2020-08-18)
Methylmercury (MeHg) is a ubiquitous environmental contaminant and developmental toxicant known to cause a variety of persistent motor and cognitive deficits. While previous research has focused predominantly on neurotoxic MeHg effects, emerging evidence points to a myotoxic role whereby MeHg
Mercury(II) Chloride.
Koc ovsky P.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Eagleson M.
Concise Encyclopedia Chemistry, 498-498 (1994)
Vasco Branco et al.
Free radical biology & medicine, 52(4), 781-793 (2011-12-27)
Mercury compounds exert toxic effects via interaction with many vital enzymes involved in antioxidant regulation, such as selenoenzymes thioredoxin reductase (TrxR) and glutathione peroxidase (GPx). Selenium supplementation can reactivate the mercury-inhibited TrxR and recover the cell viability in vitro. To
Igor Shuryak et al.
Scientific reports, 9(1), 11361-11361 (2019-08-08)
Exposure to chronic ionizing radiation (CIR) from nuclear power plant accidents, acts of terrorism, and space exploration poses serious threats to humans. Fungi are a group of highly radiation-resistant eukaryotes, and an understanding of fungal CIR resistance mechanisms holds the

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